Polymer Science

Article Engineering, Chemical

Superhydrophilic fluorinated heterogeneous membranes with boosting antifouling property and high stable permeance for efficient emulsion separation

Lulu Wang, Jie Liu, Ruilong Zhang, Junda Wu, Xiaohua Tian, Li Chen, Xiaohui Dai, Yongsheng Yan, Jianming Pan, Jiangdong Dai

Summary: This study proposes a new method to construct chemically heterogeneous superwetting membranes with high permeability and anti-fouling capability through bio-adhesion and self-assembly strategy.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Incorporating amphiphilic modifier into PVDF membrane through in-situ electrostatic crosslinking for efficient oil-water separation

Yurong Jiang, Mengying Long, Chao Yang, Shiyu Zhang, Zixuan Zhang, Cuiting Ding, Runnan Zhang, Zhongyi Jiang

Summary: Stable amphiphilic membrane surfaces were constructed using an in-situ electrostatic crosslinking method, resulting in high water permeance and superior antifouling performance for oil-water separation. The membrane also exhibited excellent structural stability and self-cleaning properties.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Electroconvective instability at the surface of one-dimensionally patterned ion exchange membranes

Jinwoong Choi, Myeonghyeon Cho, Joonghan Shin, Rhokyun Kwak, Bumjoo Kim

Summary: This study investigates the induction of overlimiting current in high voltage applications through the development of an electroconvective vortex. The dynamics of the vortex are controlled using a one-dimensional grid-patterned ion exchange membrane (IEM). The research shows that the electric potential fall rate increases rapidly during vortex development and decreases gradually during vortex merging. The study also demonstrates the successful performance of the 1D grid-patterned IEMs in terms of overlimiting currents and desalination.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Defect-free asymmetric Matrimid® gas separation membranes using dihydrolevoglucosenone (Cyrene™) as a greener polar aprotic solvent than traditional solvents

Alexander T. Bridge, Noah P. Wamble, Matthew S. Santoso, Joan F. Brennecke, Benny D. Freeman

Summary: This study demonstrates the reproducible preparation of high-flux defect-free asymmetric gas separation membranes using Cyrene(TM) as a majority dope formulation component. By adjusting the volume ratios of Cyrene(TM) and THF, as well as the concentrations of Matrimid(R) and the dry step time, optimal membrane performance is achieved.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Estimating Gas Sorption In Polymeric Membranes From The Molecular Structure: A Machine Learning Based Group Contribution Method For The Non-Equilibrium Lattice Fluid Model (ML-GC-NELF)

Hasan Ismaeel, David Gibson, Eleonora Ricci, Maria Grazia De Angelis

Summary: In this study, a machine learning-based group contribution method (ML-GC) was developed to predict pure polymer parameters and successfully applied to predict gas solubility and gas solubility isotherms in glassy polymeric membranes. The model showed satisfactory performance on a small dataset, but has the potential to provide more accurate predictions for a wider range of polymers as more data becomes available.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Biofouling metallic membranes in algae-laden water treatment: Performance, mechanism, and the role of the pre-coated layer

Yu Zhou, Dawei Zhang, Xin Song, Liqing Ma, Wanqi Qi, Weiying Li

Summary: This study investigated the application and biofouling behavior of metallic membranes in the treatment of algae-laden water. The findings show that metallic membranes can effectively remove algal cells and macromolecular organics, but have limited effects on micromolecules. The presence of algae and organics can lead to membrane fouling and decline in flux. The application of a pre-coated layer can significantly reduce membrane fouling.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Engineering antifouling membrane with surface segregation agents bearing crosslinked low surface energy segments

Zhao Zhang, Yanan Liu, Xiaocui Wei, Zongmei Li, Fu Zhao, Chunyang Fan, Yuhan Yang, Zhongyi Jiang

Summary: In this study, an antifouling membrane was successfully prepared using amphiphilic crosslinked surface segregation agents. The membrane had hydrophilic microdomains and low surface energy microdomains, leading to underwater superoleophobicity. The flux of the membrane slightly increased and the flux recovery ratio remained high. This research provides a new approach to utilizing low surface energy materials for fabricating anti-fouling membranes.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Streamlining manufacture of high-performance SiC catalytic membrane using bifunctional precursors for multipollutant control

Jiahao Chen, Yongliang Yin, Yiqing Zeng, Yarong Fang, Ze-Xian Low, Zhaoxiang Zhong, Weihong Xing

Summary: SiC catalytic membranes have great potential for controlling high-temperature NO and PM. This study proposes a novel and rapid fabrication method, using co-sintering and acid treatment, to simplify the manufacturing process, reduce energy consumption and sintering time. The resulting A-Co-SiC catalytic membrane exhibits remarkable gas permeance, superior NO oxidation efficiency, and high PM2.5 filtration efficiency.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

r-HGO/MXene composite membrane with enhanced permeability and rejection performance for water treatment

Jiawei Hou, Shixuan Guo, Nigel Graham, Wenzheng Yu, Kening Sun, Ting Liu

Summary: A novel 2D composite membrane based on r-HGO and MXene materials was developed, demonstrating exceptional performance for water treatment in terms of permeability, pollutant rejection, and physical stability. The optimization of preparation conditions and material proportions can result in high water flux and efficient removal of pollutants.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Water vapor sorption and transport in carbon molecular sieve membranes

Horacio Lopez-Marques, Kristofer L. Gleason, Manuel Aguilar-Vega, Rita Sulub-Sulub, J. Ehren Eichler, Hyeonji Oh, C. Buddie Mullins, Benny D. Freeman, Manish Kumar

Summary: In this study, water transport properties in Carbon Molecular Sieve (CMS) membranes were investigated. It was found that membranes synthesized at different pyrolysis temperatures exhibited varying water permeabilities. Compared to other polymeric materials, CMS membranes showed high water permeability, indicating potential for dehydration applications.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Polyelectrolyte multilayers modification of nanofiltration membranes to improve selective separation of mono- and multivalent cations in seawater brine

Mohammad Reza Moradi, Arto Pihlajamaki, Mehrdad Hesampour, Mariana Figueira, Monica Reig, Jose Luis Cortina, Cesar Valderrama, Mika Manttari

Summary: Nowadays, brine produced in RO seawater desalination plants is an important and underutilized source of critical minerals and metals. By using nanofiltration membranes and the Layer-by-Layer technique, polyamide NF membranes can be modified to separate brine into monovalent and multivalent ion-rich streams. The study found that Desal-5 DL membrane coated with 5.5 bilayers provided the highest selectivity factors and average rejection rate for multivalent cations.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Constructing a tannic-Fe interlayer via a simple in-situ method to enhance the filtration performance of hollow fiber organic solvent nanofiltration membranes

Liyang Liu, Shaoxiao Liu, Enlin Wang, Qiang Dong, Honghai Li, Baowei Su

Summary: In this study, a simple method was proposed to in-situ construct a tannic acid-Fe interlayer on the surface of an HF ultrafiltration membrane, resulting in improved filtration performance, operation stability, and chemical stability.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Engineering soft nanochannels in isoporous block copolymer nanofiltration membranes for ion separation

Zhenzhen Zhang, Md. Mushfequr Rahman, Ivonne Ternes, Barbara Bajer, Volker Abetz

Summary: This study reports on the development of positively charged isoporous block copolymer nanofiltration membranes with designed soft nanochannels. The membranes were obtained through self-assembly and non-solvent-induced phase separation. A versatile post-modification approach was used to engineer well-defined soft nanochannels. The membranes demonstrated the capability to separate mono-/divalent cations based on their ionic size difference, charge, and energy. The selectivity of the membranes was significantly higher in binary-salt systems compared to single-salt systems. The membranes also showed potential for recovering valuable ionic species from water, such as Mg, which is classified as a critical raw material in Europe.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Methods to modify supersaturation rate in membrane distillation crystallisation: Control of nucleation and crystal growth kinetics (including scaling)

A. Ouda, Y. Bajon-Fernandez, E. Mcadam

Summary: This study introduces a method to characterize the kinetics of nucleation and crystal growth in membrane distillation crystallisation (MDC) by considering multiple conditional parameters. The results show that modifying these parameters can increase supersaturation rate and control crystal size distribution. The findings suggest that MDC offers a scalable solution for crystallisation.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Engineering, Chemical

Nanofiber composite ultrafiltration membrane functionalized with cross-linked β-cyclodextrin for steroid hormone micropollutant removal

Alessandra Imbrogno, Han Ya Lin, Babak Minofar, Andrea Iris Schaefer

Summary: In this study, a composite nanofiber membrane containing cross-linked beta-cyclodextrin-epichlorohydrin was prepared and evaluated for the removal of steroid hormones. The results showed that the membrane had high adsorption capacity and the ability to form a specific inclusion complex interaction with the hormones, indicating its potential application in hormone removal.

JOURNAL OF MEMBRANE SCIENCE (2024)

Article Chemistry, Applied

High-throughput intact Glycopeptide quantification strategy with targeted-MS (HTiGQs-target) reveals site-specific IgG N-glycopeptides as biomarkers for hepatic disorder diagnosis and staging

Xuejiao Liu, Bin Fu, Jierong Chen, Zhenyu Sun, Dongdong Zheng, Zhonghua Li, Bing Gu, Ying Zhang, Haojie Lu

Summary: Liver disease is a major cause of global mortality, and identifying biomarkers for diagnosing its progression is crucial for improving outcomes. Targeted mass spectrometry is a powerful tool for verifying biomarker candidates and clinical applications, particularly for glycoproteins translation. However, the limitation of analyzing only one sample per run has become apparent. In this study, a high-throughput intact N-glycopeptides quantification strategy was developed, allowing the validation of 20 samples per run with an average analysis time of 3 minutes per sample. The strategy was applied in a cohort of 461 serum samples and identified a panel of 10 IgG N-glycopeptides that have strong clinical utility in evaluating the severity of liver disease.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Treatment and mechanism for hot melting starch by reducing the molecular chain winding and crystallinity

Shen Wang, Yanhui Li, Jingxian Zhang, Jia Man, Yanyan Nie, Maocheng Ji, Heyu Chen, Fangyi Li, Chuanwei Zhang

Summary: In this study, enzymatic thermoplastic starch (ETPS) was successfully obtained by combining alpha-amylase liquefaction and urea plasticization, which can undergo hot melting. ETPS showed improved elongation at break and reduced crystallinity.

CARBOHYDRATE POLYMERS (2024)

Review Chemistry, Applied

Exploitation of function groups in cellulose materials for lithium-ion batteries applications

Yuanyuan Xia, Xinping Li, Jingshun Zhuang, Wenliang Wang, Syed Comail Abbas, Chenglong Fu, Hui Zhang, Ting Chen, Yue Yuan, Xingjin Zhao, Yonghao Ni

Summary: This review thoroughly examines the current research status of cellulose-based materials for lithium-ion batteries (LIBs) components, with a specific focus on the impact of functional groups in cellulose-based separators. The study reveals that certain functional groups play a crucial role in improving the mechanical, thermal, and electrical properties of the separators. It highlights the importance of understanding the influence of functional groups in cellulose-based materials on LIBs performance.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Tailoring the surface charges of iron-crosslinked dextran nanogels towards improved tumor-associated macrophage targeting

Hong Deng, Xue Yang, Huimin Wang, Menghan Gao, Yiyi Zhang, Runmeng Liu, Haiyan Xu, Weiqi Zhang

Summary: This study demonstrates the potential of positively charged dextran nanogels (NGs) as a promising approach for TAM targeting in cancer therapy. By utilizing a non-covalent self-assembly strategy, the researchers constructed oppositely charged NGs and compared their effects on TAM targeting. The positive NGs showed superior TAM targeting in a murine breast cancer model.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Triple physical cross-linking cellulose nanofibers-based poly(ionic liquid) hydrogel as wearable multifunctional sensors

Dong Fu, Yang Xie, Lili Zhou, Lili Zhang, Ting Zheng, Jun Shen

Summary: A novel triple physical cross-linking poly(ionic liquid) hydrogel was synthesized with excellent mechanical properties and other advantages. It was assembled as a multifunctional sensor to monitor joint motion, vocal cord vibration, tactile sensation, and body temperature in real time.

CARBOHYDRATE POLYMERS (2024)