Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Nhat-Minh Phung, Minh-Tan Ha, Si-Young Bae, Soonil Lee, Tae-Joo Park, Se-Hun Kwon, Seong-Min Jeong
Summary: This study proposes a growth kinetics model for ZrO2 in atomic layer deposition (ALD) using a mixed alkylamidocyclopentadienyl zirconium precursor. The model is based on experimental data and evaluates film growth behavior using reactor-scale simulation. The study finds that the adsorption of Cp-Zr molecules is hindered by the bulkiness of remaining ligands on adsorbed species. The hindrance effect is significant at temperatures between 150°C and 250°C, but decreases with increasing temperature and disappears at 300°C. The research provides valuable insights for optimizing ALD deposition processes of high-k metal oxides.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Dhandayuthapani Thiyagarajan, Shichen Li, Sivaselvam Subramani, Arun Thirumurugan, Bong-Kee Lee
Summary: Metal-organic frameworks (MOFs) are explored as a precursor for producing porous metal oxide-supported nitrogen-doped carbon nanomaterials. In this study, nanocrystalline titanium dioxide-supported nitrogen-doped carbon nanostructures (TiO2@NC) were fabricated from a titanium MOF and showed efficient removal of tetracycline (TC) in aqueous solutions. The TiO2@NC nanospheres exhibited high adsorption capacity, broad pH range suitability, and excellent stability. The adsorption process was influenced by nitrogen sites, surface area, and porous sphere morphology.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jie Yang, Ren Wang, Jinsheng Sun, Yuanzhi Qu, Han Ren, Zhiliang Zhao, Pingquan Wang, Yingying Li, Luman Liu
Summary: This study successfully synthesized P-LDH composites with partially intercalated and partially exfoliated structures by in-situ polymerization. The P-LDH showed excellent thermal stability and low viscosity effect, which significantly reduced the filtrate loss of drilling fluids under ultrahigh-temperature and high-salt conditions.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qingquan Xue, Bingtao Song, Qian Feng, Zhuofan Yu, Kaiwei Hu, Ye Yang, Xiaofeng Shen
Summary: In this study, the growth of magnetic recyclable FeOOH nanoneedles on biochar surface was achieved for efficient treatment of antibiotic wastewater. The presence of H2O2 promoted the recycling of Fe3+/Fe2+, leading to enhanced photocatalytic and photo-Fenton catalytic performance. The potential degradation mechanism and pathway were investigated, and the magnetic FeOOH nanoneedles demonstrated remarkable reusability and cycling capability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qing Lu, Shuli Wei, Guangchao Yin, Peikang Bai, Yuxin Li
Summary: Dy-doped hexagonal boron nitride nanosheets were prepared through high-temperature reduction reactions. The nanosheets exhibited room-temperature ferromagnetism and semiconductor conductivity. The doping of Dy transformed the nanosheets from insulators to magnetic semiconductors.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Sheng Liang, Yiwei Zhang, Kunhong Hu, Miaoxin Chen, Ningning Zhou, Lei Hu, Yaxiong Yang, Lili Wang, Xin Liang, Yanxia Liu, Chu Liang, Hongge Pan
Summary: In this study, a multi-functional host of MoC quantum dots embedded in N-doped 2D nanocarbon (MoC@2D-NNC) was reported for improving the performance of Li2S batteries. The MoC@2D-NNC/Li2S composite was prepared via easy liquid-phase dissolution precipitation and exhibited excellent conductivity and cycling performance, showing potential applications.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhipeng Wu, Xi Huang, Wanting Sun, Haoyu Dong, Aofei Mao, Bai Cui, Jean-Francois Silvain, Xinwei Wang, Yongfeng Lu
Summary: This study explored the use of nanosecond laser pulses for laser-induced sub-surface evaporation as a promising alternative for surface drying. By adjusting the laser fluence, clean and dry substrates can be obtained without any stain or damage. The effectiveness of laser drying was evaluated on various substrates, and the results indicate that pulsed lasers can be a versatile and environmentally friendly drying tool.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jinwei Wei, Youzhuang Rong, Changmin Wang, Mingjie Lv, Yongkang Yang, Zhao Li, Yonghui Zhang, Gongxiang Wei, Yunyan Liu, Mianzeng Zhong, Huiqiang Liu
Summary: CsPb2Cl5 nanosheets were successfully grown on various substrates using a simple solution method. The growth of the nanosheets was found to be influenced by temperature, with lower temperatures promoting nucleation. The nanosheets exhibited large Stokes shift, broad emission spectrum, and prolonged carrier lifetime, making them suitable for applications such as UV photodetectors.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Gabriel T. Dos Santos, Karen C. Bedin, Tanna E. R. Fiuza, Ingrid Rodriguez-Gutierrez, Paulo F. P. Fichtner, Flavio L. Souza, Jefferson Bettini
Summary: This study investigates the effects of adding Zr4+ and Ni2+ on the performance of hematite photoanode thin films in the photoelectrochemical hydrogen production process. Chemical mapping reveals the preferential segregation of Zr4+ at the interface and grain boundaries, while Ni2+ is mainly present on the hematite-free surfaces. The introduction of Zr4+ improves the back contact, facilitating electron collection and flow through the external circuit. Structural analysis also shows lattice distortions and strain field accumulation at the interface region.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Tzu-Ho Wu, Zi-Ting Qiu, Chih-Ning Hsieh
Summary: This study successfully synthesized a NiP/CNTs/NF electrocatalyst through a simple method and demonstrated its excellent electrocatalytic performance in urea electrolysis, paving the way for obtaining highly efficient electrocatalysts.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Haili Huang, Zhentao Du, Hung-Chun Wu, Fengmei Gao, Lan Jiang, Huilin Hou, Shanliang Chen, Weijun Li, Feng Hu, Weiyou Yang, Dongdong Zhang, Lin Wang
Summary: In this study, a high-temperature resistant ethanol sensor based on rationally designed heterojunctions is constructed, exhibiting significantly improved performance in sensing ethanol at 465 degrees C. The sensor demonstrates high response, fast detection, and excellent selectivity, suggesting promising applications for stable sensors operating under harsh working conditions.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Paula Navascues, Martina Buchtelova, Lenka Zajickova, Patrick Rupper, Dirk Hegemann
Summary: This study reveals the influence of diffusion of film forming species and surface reactivity in HMDSO plasmas by studying two different geometries. The results indicate different sticking probabilities of film-forming species and suggest that high-energy particles may contribute to film formation underneath small openings.
APPLIED SURFACE SCIENCE
(2024)