Materials Science, Multidisciplinary

Article Chemistry, Physical

Single-junction organic solar cells with over 19% efficiency enabled by a refined double-fibril network morphology

Lei Zhu, Ming Zhang, Jinqiu Xu, Chao Li, Jun Yan, Guanqing Zhou, Wenkai Zhong, Tianyu Hao, Jiali Song, Xiaonan Xue, Zichun Zhou, Rui Zeng, Haiming Zhu, Chun-Chao Chen, Roderick C. MacKenzie, Yecheng Zou, Jenny Nelson, Yongming Zhang, Yanming Sun, Feng Liu

Summary: Morphological control of donor and acceptor domains is crucial for efficient organic photovoltaics, and this study demonstrates a double-fibril network strategy to achieve a high power conversion efficiency of 19.3%.

NATURE MATERIALS (2022)

Review Chemistry, Multidisciplinary

Emerging S-Scheme Photocatalyst

Liuyang Zhang, Jianjun Zhang, Huogen Yu, Jiaguo Yu

Summary: This article presents the superiority and design criteria of the emerging S-scheme heterojunction in photocatalysis. By overcoming the challenges faced by single photocatalysts through the construction of heterojunctions, the S-scheme heterojunction has demonstrated its potential in improving photocatalysis. The critical understanding of the curved Fermi level in the S-scheme heterojunction interface and the current challenges and prospects of S-scheme heterojunction photocatalysts are also discussed.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

Tandem Organic Solar Cell with 20.2% Efficiency

Zhong Zheng, Jianqiu Wang, Pengqing Bi, Junzhen Ren, Yafei Wang, Yi Yang, Xiaoyu Liu, Shaoqing Zhang, Jianhui Hou

Summary: A advanced interconnecting layer for tandem organic solar cell is developed in this study. By controlling the O-2 flux during evaporation, efficient electron extraction and low Schottky barrier are obtained, enabling effective charge recombination between two subcells. The tandem cell with the interconnecting layer shows a high efficiency of 20.27%.
Article Chemistry, Multidisciplinary

Realizing 19.05% Efficiency Polymer Solar Cells by Progressively Improving Charge Extraction and Suppressing Charge Recombination

Kaien Chong, Xiaopeng Xu, Huifeng Meng, Jingwei Xue, Liyang Yu, Wei Ma, Qiang Peng

Summary: This work demonstrates highly efficient polymer solar cells by improving charge extraction and suppressing charge recombination through side-chain engineering, adopting ternary blends, and introducing volatilizable solid additives. The optimized molecular structure and blend morphology lead to improved fill factor and power conversion efficiency.

ADVANCED MATERIALS (2022)

Review Nanoscience & Nanotechnology

Bioplastics for a circular economy

Jan-Georg Rosenboom, Robert Langer, Giovanni Traverso

Summary: Bioplastics have the potential to contribute to a more sustainable and circular economy by reducing carbon footprint and offering advantageous material properties. However, they also face challenges such as negative agricultural impacts, competition with food production, unclear end-of-life management, and higher costs. Emerging chemical and biological methods can enable the upcycling of plastic waste into higher-quality materials. Standardization and guidelines are needed to guide purchasing choices, and clear regulations and financial incentives are essential for the large-scale adoption of bioplastics in a truly sustainable manner.

NATURE REVIEWS MATERIALS (2022)

Review Chemistry, Physical

Design concept for electrocatalysts

Yao Wang, Xiaobo Zheng, Dingsheng Wang

Summary: Metal-based electrocatalysts with different sizes have shown different catalytic behaviors, and regulating the coordination environment of active sites is crucial for designing efficient electrocatalysts. This review summarizes the recent progress in heterogeneous supported single atoms, nanoclusters, and nanoparticles catalysts, proposing key factors for enhancing electrocatalytic performance and discussing current challenges and future opportunities in this field.

NANO RESEARCH (2022)

Article Chemistry, Multidisciplinary

Single-Junction Organic Solar Cells with 19.17% Efficiency Enabled by Introducing One Asymmetric Guest Acceptor

Rui Sun, Yao Wu, Xinrong Yang, Yuan Gao, Zeng Chen, Kai Li, Jiawei Qiao, Tao Wang, Jing Guo, Chao Liu, Xiaotao Hao, Haiming Zhu, Jie Min

Summary: The ternary strategy is an effective approach to achieve high-efficiency OSCs, but the nonradiative voltage loss limits further efficiency improvements. By incorporating an asymmetric guest acceptor BTP-2F2Cl, the OSCs show improved photoluminescence quantum yield, exciton diffusion length, and absorption spectrum, leading to enhanced power conversion efficiency.

ADVANCED MATERIALS (2022)

Review Chemistry, Multidisciplinary

Dimensional Design and Core-Shell Engineering of Nanomaterials for Electromagnetic Wave Absorption

Zhengchen Wu, Han-Wen Cheng, Chen Jin, Bintong Yang, Chunyang Xu, Ke Pei, Huibin Zhang, Ziqi Yang, Renchao Che

Summary: Electromagnetic wave absorption materials with core-shell structures can enhance performance through interfacial polarization, conduction networks, magnetic coupling, and magnetic-dielectric synergy. This review outlines the recent advances in low-dimensional core-shell electromagnetic wave absorption materials and discusses notable examples. Key information regarding dimensional design, structural engineering, performance, and structure-function relationship is comprehensively summarized.

ADVANCED MATERIALS (2022)

Review Chemistry, Multidisciplinary

Dielectric Loss Mechanism in Electromagnetic Wave Absorbing Materials

Ming Qin, Limin Zhang, Hongjing Wu

Summary: Comprehensive views on dielectric loss mechanisms provide important guidance for understanding the attenuation behavior of materials. Current researches focus more on materials synthesis rather than in-depth mechanism study. Therefore, further research on in-depth mechanisms, emphasis on new dielectric loss mechanisms, and new modulation strategies are needed to achieve simple and effective EM wave attenuation behavior modulation.

ADVANCED SCIENCE (2022)

Review Materials Science, Multidisciplinary

High-entropy alloys with heterogeneous microstructure: Processing and mechanical properties

Praveen Sathiyamoorthi, Hyoung Seop Kim

Summary: Engineering metallic materials with excellent mechanical properties, especially strength and ductility, are highly sought after for various applications. Novel approaches to enhance strength-ductility synergy through heterogeneous microstructures have proven effective in overcoming the traditional strength-ductility trade-off. The discovery of high entropy alloys based on multi-principal elements offers wider possibilities for alloy design and the exploration of new alloys with remarkable properties.

PROGRESS IN MATERIALS SCIENCE (2022)

Article Chemistry, Physical

Understanding the structure-performance relationship of active sites at atomic scale

Runze Li, Dingsheng Wang

Summary: This article discusses the key factors affecting the catalytic performance of metal-based atomically dispersed catalysts and their relationship with the active sites. It first introduces the effectiveness of active site design through coordination effects, then discusses the role of chemical bonds in the active sites and the influence of the spacing of active atoms in intermetallic compounds on catalytic behavior. Additionally, the importance of synergistic effects in catalyst design is emphasized, and the key parameters affecting catalytic performance at the atomic scale are summarized.

NANO RESEARCH (2022)

Article Chemistry, Multidisciplinary

pH/Glucose Dual Responsive Metformin Release Hydrogel Dressings with Adhesion and Self-Healing via Dual-Dynamic Bonding for Athletic Diabetic Foot Wound Healing

Yongping Liang, Meng Li, Yutong Yang, Lipeng Qiao, Huiru Xu, Baolin Guo

Summary: A dual-responsive hydrogel dressing was constructed for the treatment of type II diabetic foot ulcers and shown to promote wound healing in a rat model. The addition of metformin and graphene oxide further enhanced wound repair.

ACS NANO (2022)

Review Chemistry, Multidisciplinary

Heterointerface Engineering in Electromagnetic Absorbers: New Insights and Opportunities

Leilei Liang, Weihua Gu, Yue Wu, Baoshan Zhang, Gehuan Wang, Yi Yang, Guangbin Ji

Summary: Electromagnetic absorbers are playing increasingly essential role in the electronic information age and even towards the coming intelligent era. The advantages of heterointerface engineering and its EM characteristics inject vitality for designing high-efficiency EM absorbers, but there are still huge challenges in understanding and reinforcing these interface effects.

ADVANCED MATERIALS (2022)

Article Materials Science, Multidisciplinary

Theory-oriented screening and discovery of advanced energy transformation materials in electrocatalysis

Hongyu Jing, Peng Zhu, Xiaobo Zheng, Zedong Zhang, Dingsheng Wang, Yadong Li

Summary: This review comprehensively outlines the latest progress of theory-guided design of advanced energy transformation materials, with a focus on the study of single atoms in various power devices and electrocatalytic conversion reactions related to energy. The electronic structure, interaction mechanism, and reaction activation path are discussed, and experimental synthesis strategies, structural recognition, and electrocatalytic performance are determined. Some viewpoints into the current issues and future design concept are also provided.

ADVANCED POWDER MATERIALS (2022)

Article Chemistry, Multidisciplinary

Binary Organic Solar Cells Breaking 19% via Manipulating the Vertical Component Distribution

Yanan Wei, Zhihao Chen, Guanyu Lu, Na Yu, Congqi Li, Jinhua Gao, Xiaobin Gu, Xiaotao Hao, Guanghao Lu, Zheng Tang, Jianqi Zhang, Zhixiang Wei, Xin Zhang, Hui Huang

Summary: The variation of the vertical component distribution has a significant impact on the photovoltaic performance of organic solar cells. This study demonstrates that sequential deposition of materials can improve the efficiency of solar cells.

ADVANCED MATERIALS (2022)

Article Energy & Fuels

Solar cell efficiency tables (Version 60)

Martin A. Green, Ewan D. Dunlop, Jochen Hohl-Ebinger, Masahiro Yoshita, Nikos Kopidakis, Karsten Bothe, David Hinken, Michael Rauer, Xiaojing Hao

Summary: This article presents consolidated tables showing the highest independently confirmed efficiencies for solar cells and modules. The guidelines for including results in these tables are outlined, and new entries since January 2022 are reviewed. An appendix describing temporary electrical contacting methods and terminology for large-area solar cells is also included.

PROGRESS IN PHOTOVOLTAICS (2022)

Article Chemistry, Multidisciplinary

Nanochemistry approach for the fabrication of Fe and N co-decorated biomass-derived activated carbon frameworks: a promising oxygen reduction reaction electrocatalyst in neutral media

Hassan Karimi-Maleh, Ceren Karaman, Onur Karaman, Fatemeh Karimi, Yasser Vasseghian, Li Fu, Mehdi Baghayeri, Jalal Rouhi, P. Senthil Kumar, Pau-Loke Show, Saravanan Rajendran, Afsaneh L. Sanati, Ali Mirabi

Summary: This study successfully improved the performance of the oxygen reduction reaction (ORR) in neutral media by tailoring a biomass-derived ORR electrocatalyst. The iron- and nitrogen-doped activated carbon framework showed superior ORR activity and long-term stability. The catalyst also demonstrated lower onset potential and better resistance to sulfur poisoning compared to the traditional platinum-based catalyst, paving the way for the development of low-cost nanocatalysts.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2022)

Review Materials Science, Multidisciplinary

The light of carbon dots: From mechanism to applications

Boyang Wang, Siyu Lu

Summary: This review discusses the preparation and optical properties of carbon dots (CDs), which are an important type of nanomaterial with wide applications in optoelectronic devices and biomedicine. The review explores the fluorescence mechanism and preparation methods of CDs, and highlights the adjustment of CD afterglow emission. Additionally, the review discusses the important optical applications of CDs and presents future research directions and potential challenges.

MATTER (2022)

Article Energy & Fuels

Rational solvent molecule tuning for high-performance lithium metal battery electrolytes

Zhiao Yu, Paul E. Rudnicki, Zewen Zhang, Zhuojun Huang, Hasan Celik, Solomon T. Oyakhire, Yuelang Chen, Xian Kong, Sang Cheol Kim, Xin Xiao, Hansen Wang, Yu Zheng, Gaurav A. Kamat, Mun Sek Kim, Stacey F. Bent, Jian Qin, Yi Cui, Zhenan Bao

Summary: The authors designed and synthesized a family of fluorinated-1,2-diethoxyethanes as electrolyte solvents, addressing the issue of cycling capability in lithium metal batteries and uncovering the relationship between electrolyte structure and performance.

NATURE ENERGY (2022)

Review Materials Science, Multidisciplinary

Multifunctional applications of biochar beyond carbon storage

Nanthi Bolan, Son A. Hoang, Jingzi Beiyuan, Souradeep Gupta, Deyi Hou, Ajay Karakoti, Stephen Joseph, Sungyup Jung, Ki-Hyun Kim, M. B. Kirkham, Harn Wei Kua, Manish Kumar, Eilhann E. Kwon, Yong Sik Ok, Vishma Perera, Jorg Rinklebe, Sabry M. Shaheen, Binoy Sarkar, Ajit K. Sarmah, Bhupinder Pal Singh, Gurwinder Singh, Daniel C. W. Tsang, Kumar Vikrant, Meththika Vithanage, Ajayan Vinu, Hailong Wang, Hasintha Wijesekara, Yubo Yan, Sherif A. Younis, Lukas Van Zwieten

Summary: Biochar is a charred material with high surface area and abundant functional groups produced by pyrolysis, and it has multifunctional values when applied in soil, but may also lead to unintended consequences.

INTERNATIONAL MATERIALS REVIEWS (2022)