Materials Science, Coatings & Films

Article Materials Science, Coatings & Films

The influence of the H/E ratio on wear resistance of coating systems - Insights from small-scale testing

Ben D. Beake

Summary: The study explores the correlation between the ratio of hardness to elastic modulus (H/E) of coating systems and their wear resistance. It discusses experimental approaches to determine accurate H/E values and summarises best practice recommendations. Case studies demonstrate the importance of relatively low coating elastic modulus in reducing tensile stresses.

SURFACE & COATINGS TECHNOLOGY (2022)

Article Chemistry, Applied

Investigation of Electrophoretic Deposition of PANI Nano fibers as a Manufacturing Technology for corrosion protection

Mohammed Fuseini, Moustafa Mahmoud Yousry Zaghloul

Summary: This study describes the electrophoretic deposition process of polyaniline film using three models and analyzes its effects on film properties. The results show a linear deposition growth law and a transition in deposition mechanism from linear mode to parabolic.

PROGRESS IN ORGANIC COATINGS (2022)

Article Chemistry, Physical

Revealing the strong interaction effect of MnOx nanoparticles and Nb2O5 supports with variable morphologies on catalytic propane oxidation

Yating Wang, Chao Wang, Kai Zeng, Shuoming Wang, Hongliang Zhang, Xiaowen Li, Zhong Wang, Chuanhui Zhang

Summary: The study demonstrates that different morphologies of Nb2O5 supports significantly influence the catalytic activity of MnOx catalysts, with the layer-like morphology of MnOx/Nb2O5-L showing the best performance. However, MnOx/Nb2O5-L exhibits good surface dispersion and strong metal-support interaction, but suffers from irreversible deactivation after long-term catalytic reactions.

APPLIED SURFACE SCIENCE (2022)

Article Materials Science, Multidisciplinary

Mesoporous activated carbon from mangosteen (Garcinia mangostana) peels by H3PO4 assisted microwave: Optimization, characterization, and adsorption mechanism for methylene blue dye removal

Ali H. Jawad, Shihab Ezzuldin M. Saber, Ahmed Saud Abdulhameed, Abdallah Reghioua, Zeid A. ALOthman, Lee D. Wilson

Summary: This study reported a facile method to synthesize mangosteen peels activated carbon (MSPAC) with high carbon content and mesoporous structure. MSPAC showed excellent adsorption capability for methylene blue (MB) dye removal from aqueous solutions. The optimization of adsorption conditions using response surface methodology resulted in the best parameters for maximum MB removal. The kinetic and equilibrium results were best represented by the PSO and Langmuir models, respectively. Thermodynamic findings indicated that the adsorption process was spontaneous and endothermic. This work highlights the significance of MSPAC as an environmentally friendly adsorbent for removing cationic synthetic dyes from polluted water.

DIAMOND AND RELATED MATERIALS (2022)

Article Materials Science, Multidisciplinary

High sensitivity active adjustable graphene absorber for refractive index sensing applications

Qianyi Shangguan, Yong Zhao, Zijun Song, Jian Wang, Hua Yang, Jing Chen, Chao Liu, Shubo Cheng, Wenxing Yang, Zao Yi

Summary: In this paper, a three-band active adjustable perfect absorber with multiple advantages, such as multi-band perfect absorption, active adjustability, and high refractive index sensitivity, is proposed. The absorber exhibits good and stable sensing performance and has specific applications in the medical field.

DIAMOND AND RELATED MATERIALS (2022)

Article Materials Science, Coatings & Films

Fluorine-free fabrication of robust self-cleaning and anti-corrosion superhydrophobic coating with photocatalytic function for enhanced anti-biofouling property

Hao Li, Lei Xin, Kai Zhang, Xiaoli Yin, Sirong Yu

Summary: A fluorine-free robust superhydrophobic coating was fabricated on Al alloy substrate using a simple and low-cost approach. The prepared coating with hierarchical structures, re-entrant structures, and low surface energy exhibited superhydrophobicity. The coating showed excellent stability, enhanced adhesive strength, self-cleaning property, and anti-corrosion capabilities. Additionally, the combination of superhydrophobic and photocatalytic properties improved the anti-biofouling performance of the Al alloy substrate.

SURFACE & COATINGS TECHNOLOGY (2022)

Article Chemistry, Physical

Composite material CCO/Co-Ni-Mn LDH made from sacrifice template CCO/ZIF-67 for high-performance supercapacitor

Chen Hao, Xiaokun Wang, Xingli Wu, Yaning Guo, Linli Zhu, Xiaohong Wang

Summary: A composite material CCO/CNM combining cotton carbon and metal organic framework was successfully prepared and showed excellent electrochemical properties with high specific capacitance and good cycle stability. The assembled asymmetric supercapacitor exhibited superior energy density and cycling performance, successfully lighting up LED bulbs.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Efficient photocatalytic H2 evolution over 2D/2D S-scheme NiTe2/g-C3N4 heterojunction with superhydrophilic surface

Qiqi Zhang, Xue Bai, Xiaoyun Hu, Jun Fan, Enzhou Liu

Summary: This study achieved efficient H-2 evolution by constructing an S-scheme heterojunction, which accelerates the migration of photogenerated carriers and enhances the redox ability to improve catalytic activity.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Rational design of honeycomb Ni-Co LDH/graphene composite for remarkable supercapacitor via ultrafast microwave synthesis

Jizhao Zou, Dong Xie, Jingyou Xu, Xinrui Song, Xierong Zeng, Hongbin Wang, Fenglin Zhao

Summary: In this study, a high-efficiency microwave liquid synthesis method was used to prepare Ni-Co LDH/G composite, which improved the conductivity and rate capability of Ni-Co LDH. The findings suggest that microwave synthesis could be an efficient route to engineer advanced electrode materials for supercapacitors.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Referencing to adventitious carbon in X-ray photoelectron spectroscopy: Can differential charging explain C 1s peak shifts?

G. Greczynski, L. Hultman

Summary: The peak position of C 1s can be affected by the vacuum level alignment and differential charging. However, recent studies suggest that differential charging may not be the general cause of C 1s peak shifts. Experimental results confirm that the binding energy of C 1s peaks in metal foils is determined by their work function values.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

1T-MoS2 monolayer as a promising anode material for (Li/Na/Mg)-ion batteries

Xiaojie He, Ruichen Wang, Huimin Yin, Yongfan Zhang, Wenkai Chen, Shuping Huang

Summary: Transition metal sulfides, particularly 1T-MoS2, have been explored as promising anode materials for rechargeable batteries due to their high electrical conductivity, thermal stability, and excellent electrochemical performance. Density functional theory calculations reveal strong binding between metal ions and 1T-MoS2, along with good ion diffusion rates and appropriate open-circuit voltages and specific capacities. Thus, 1T-MoS2 demonstrates great potential as an anode material for lithium-ion, sodium-ion, and magnesium-ion batteries.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Heterointerface engineering of water stable ZIF-8@ZIF-67: Adsorption of rhodamine B from water

Muhammad Altaf Nazir, Tayyaba Najam, Khurram Shahzad, Muhammad Ahmad Wattoo, Tajamal Hussain, Muhammad Khurram Tufail, Syed Shoaib Ahmad Shah, Aziz Ur Rehman

Summary: In this study, a novel bimetallic zeolitic imidazolate frameworks (ZIFs) have been fabricated for the elimination of toxic dye from water. The synthesized ZIF-8@ZIF-67 showed improved physical and chemical properties compared to single metallic MOFs (ZIF-67 and ZIF-8). Langmuir model was found to sufficiently explain the adsorption process of ZIF-8@ZIF-67, and the mean free energy suggested chemisorption dominates the adsorption. The high applicability and reusability of the bimetallic MOFs were demonstrated through the removal of rhodamine B from water.

SURFACES AND INTERFACES (2022)

Article Chemistry, Physical

A novel electrochemical kidney injury molecule-1 (KIM-1) immunosensor based covalent organic frameworks-gold nanoparticles composite and porous NiCo2S4@CeO2 microspheres: The monitoring of acute kidney injury

Havva Boyacioglu, Bahar Bankoglu Yola, Ceren Karaman, Onur Karaman, Necip Atar, Mehmet Lutfi Yola

Summary: This study describes a new method for rapid diagnosis of kidney injury. A sensitive and selective kidney injury immunosensor was fabricated using porous NiCo2S4@CeO2 microspheres as a signal amplifier and COFs-AuNPs composite as an electrochemical sensor platform. The immunosensor showed high detection sensitivity and accuracy, making it a valuable tool for monitoring acute kidney injury.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Fabrication of novel rational Ti-Sn doped Cu-ferrite nanoparticles for robust photocatalysis reaction, magnetic resonance imaging, and chemo-magneto-photo-thermal therapy

Bing Hu, Yanjun Cui, Xi Yang, Xia Xu, Baadal Jushi Janani, Ali Fakhri

Summary: This project presents the synthesis of Ti-Sn doped Cu-ferrite nanoparticles with different ratios using sol gel/precipitation route. The properties of these nanoparticles were investigated, including their X-ray diffraction analysis, degradation activity of dyes under visible light irradiation, and potential applications in magnetic resonance imaging and drug release under near infrared laser irradiation.

SURFACES AND INTERFACES (2022)

Article Chemistry, Physical

Multi-defects engineering of NiCo2O4 for catalytic propane oxidation

Mingchao Zhang, Xin Sui, Xin Zhang, Mang Niu, Cuiqing Li, Haiqin Wan, Zhen-An Qiao, Haijiao Xie, Xingyun Li

Summary: By using a mechano-chemical strategy with Na assisted milling, a multi-defective spinel catalyst D-NiCo2O4 was developed, which exhibited significantly elevated oxygen vacancies, raised active oxygen species, enhanced oxygen mobility, and increased specific surface area. This catalyst showed superb activity for propane catalytic oxidation, outperforming pristine NiCo2O4 and Co3O4 catalyst, making it one of the most outstanding non-noble metal catalysts for propane oxidation. This work set a paradigm for enhancing the VOCs oxidation performance of metal oxide catalyst by multi-defects engineering.

APPLIED SURFACE SCIENCE (2022)

Article Materials Science, Multidisciplinary

Jointing of CFRP/5083 Aluminum Alloy by Induction Brazing: Processing, Connecting Mechanism, and Fatigue Performance

Kang Guo, Guoqing Gou, Hang Lv, Meile Shan

Summary: Carbon fiber reinforced polymer (CFRP) is widely used in the lightweight design of high-speed trains. In this study, CFRP plate and 5083P-O aluminum plate were successfully joined using induction brazing. Anodization of the aluminum plate increased the wetting behavior and bonding strength between CFRP and oxide film. High-cycle fatigue testing revealed a low fatigue limit for the CFRP/5083 joint.

COATINGS (2022)

Article Chemistry, Physical

3D interconnected g-C3N4 hybridized with 2D Ti3C2 MXene nanosheets for enhancing visible light photocatalytic hydrogen evolution and dye contaminant elimination

Dong Liu, Chunling Li, Jiayu Ge, Congyue Zhao, Qian Zhao, Fengquan Zhang, Tianjun Ni, Weidong Wu

Summary: In this study, a high-efficiency 3D/2D g-C3N4/Ti3C2 heterojunction photocatalyst was designed for photocatalytic hydrogen evolution and organic dye elimination. The excellent performance of the material is attributed to its 3D interconnected porous structure and the incorporation of Ti3C2 nanosheets, providing a high specific surface area and efficient charge migration. Mechanisms for the improved photocatalytic performance were analyzed through characterization measurements, active species analysis, and density functional theory calculations.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Ab-initio-driven prediction of puckered penta-like PdPSeX (X=O, S, Te) Janus monolayers: Study on the electronic, optical, mechanical and photocatalytic properties

A. Bafekry, M. Faraji, Mohamed M. Fadlallah, H. R. Jappor, N. N. Hieu, M. Ghergherehchi, D. Gogova

Summary: A systematic investigation of puckered penta-like PdPSeX Janus monolayers reveals their stable structure and good performance in light absorption and photocatalytic water splitting, providing valuable insights for further experimental and theoretical studies.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Applied

Carboxymethyl cellulose-based functional film integrated with chitosan-based carbon quantum dots for active food packaging applications

Zohreh Riahi, Jong-Whan Rhim, Reza Bagheri, Gholamreza Pircheraghi, Ensieh Lotfali

Summary: Chitosan-based carbon quantum dots (CQDs) with multifunctional properties, including antioxidant, antibacterial, and antifungal activities, were synthesized using a hydrothermal process. The CQDs were incorporated into carboxymethyl cellulose (CMC) films, resulting in highly transparent UV-blocking films with improved tensile strength and elastic modulus. The CQD-added CMC films demonstrated excellent preservation effects on lemon fruits.

PROGRESS IN ORGANIC COATINGS (2022)

Article Chemistry, Applied

Hydrothermally synthesized ZnO-RGO-PPy for water-borne epoxy nanocomposite coating with anticorrosive reinforcement

Qingsong Zhu, Yao Zhao, Baoji Miao, Hala M. Abo-Dief, Muchao Qu, Rami Adel Pashameah, Ben Bin Xu, Mina Huang, Hassan Algadi, Xianhu Liu, Zhanhu Guo

Summary: Waterborne epoxy nanocomposite coating with hydrothermal synthesized zinc oxide-reduced graphene oxide-polypyrrole exhibited enhanced corrosion resistance and superior coating integrity. The synergistic protection mechanism of this coating includes barrier effects, chemical passivation, and electron acceptance.

PROGRESS IN ORGANIC COATINGS (2022)