Materials Science, Ceramics

Review Materials Science, Ceramics

Si-based polymer-derived ceramics for energy conversion and storage

Qingbo Wen, Fangmu Qu, Zhaoju Yu, Magdalena Graczyk-Zajac, Xiang Xiong, Ralf Riedel

Summary: This review highlights the recent progress in the field of polymer-derived ceramics (PDCs) for energy conversion and storage applications. It provides a brief introduction to the synthesis, processing, and microstructure characterization of PDCs, and summarizes their various applications in energy conversion systems and energy storage. The review also discusses possible future applications and research directions for PDCs.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Improved microwave absorption and EMI shielding properties of Ba-doped Co-Zn ferrite

Khalid Muajsam Batoo, Muhammad Hadi, Ritesh Verma, Ankush Chauhan, Rajesh Kumar, Mahavir Singh, Omar M. Aldossary

Summary: This study reports the synthesis of Ba-doped Co-Zn ferrite nanoparticles using the sol-gel auto combustion technique. Various analytical methods were used to confirm the structure, chemical purity, and physical properties of the samples. The findings showed changes in crystallite size, lattice parameter, magnetic properties, and EMI shielding effectiveness with increasing dopant concentration.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Carbonized wood with ordered channels decorated by NiCo2O4 for lightweight and high-performance microwave absorber

Guangyu Qin, Xiaoxiao Huang, Xu Yan, Yunfei He, Yuhao Liu, Long Xia, Bo Zhong

Summary: This study successfully prepared a carbonized wood-decorated NiCo2O4 composite material with an ordered channel structure, and the horizontally arranged channels exhibited high reflection loss value and effective absorption bandwidth under specific conditions. The excellent microwave absorption property is attributed to the ordered channel structure, which promotes interfacial polarization and dipole polarization, as well as multiple reflections and scattering.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Wet-chemical synthesis of nanostructured Ce-doped mixed metal ferrites for the effective removal of azo dyes from industrial discharges

Tehmina Kousar, Muhammad Aadil, Sonia Zulfiqar, Muhammad Farooq Warsi, Syeda Rabia Ejaz, Ashraf Y. Elnaggar, Ahmed M. Fallatah, Salah M. El-Bahy, Farzana Mahmood

Summary: Photocatalysis is a cost-effective and environmentally friendly technique for addressing water pollution caused by industrialization. In this study, Ce-doped cobalt/nickel mixed metal ferrite materials were synthesized using the microemulsion method. The C-9@CNMF material exhibited better mineralization of the CR dye, faster mineralization rate, and excellent recyclability and photo-corrosion resistance. These superior photocatalytic properties are attributed to the nanoarchitecture, larger specific surface area, tunable bandgap, and effective charge separation characteristics of the C-9@CNMF sample.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Designing low-carbon MgO-Al2O3-La2O3-C refractories with balanced performance for ladle furnaces

Xinming Ren, Beiyue Ma, Hao Liu, Zhoufu Wang, Chengji Deng, Guoqi Liu, Jingkun Yu

Summary: In order to achieve high-quality and stable production of special steel, the performance of low-carbon MgO-C refractories needs to be further optimized. Low-carbon MgO-Al2O3-La2O3-C refractories with enhanced thermal shock resistance and slag resistance were successfully prepared by introducing Al2O3 as a reinforcer and La2O3 as a modifier.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2022)

Article Materials Science, Ceramics

Additive manufacturing of ceramic materials for energy applications: Road map and opportunities

Corson L. Cramer, Emanuel Ionescu, Magdalena Graczyk-Zajac, Andrew T. Nelson, Yutai Katoh, Jeffery J. Haslam, Lothar Wondraczek, Trevor G. Aguirre, Saniya LeBlanc, Hsin Wang, Mansour Masoudi, Ed Tegeler, Ralf Riedel, Paolo Colombo, Majid Minary-Jolandan

Summary: This article reviews the state of the art in ceramic materials for various energy applications, focusing on material selections, processing, and opportunities for additive manufacturing technologies in energy-related ceramic materials manufacturing.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2022)

Article Materials Science, Ceramics

A new type of microwave dielectric ceramic based on K2O-SrO-P2O5 composition with high quality factor and low sintering temperature

Jian Bao, Jialun Du, Lintao Liu, Haitao Wu, Yuanyuan Zhou, Zhenxing Yue

Summary: A new type of microwave dielectric ceramics, KSrPO4, with low dielectric loss was fabricated through a traditional solid-phase method. The ceramics exhibited excellent microwave dielectric properties, suitable for use in LTCC devices. The internal parameters of KSrPO4 ceramics were calculated based on complex chemical bond theory, and their effects on properties were systematically analyzed.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Fabrication of novel SnWO4/ZnO using Muntingia calabura L. leaf extract with enhanced photocatalytic methylene blue degradation under visible light irradiation

Elviera, Yoki Yulizar, Dewangga Oky Bagus Apriandanu, Rizki Marcony Surya

Summary: In this study, a SnWO4/ZnO heterostructure was successfully constructed using Muntingia calabura L. leaf extract, demonstrating significant photocatalytic degradation of methylene blue under visible light irradiation with excellent stability. The formation of the heterostructure led to enhanced photocatalytic activity attributed to decreased optical bandgap and low recombination rate of photogenerated electron-hole pairs, showing potential for ecofriendly and cost-effective dye degradation applications.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Production of smart nanocomposite for glass coating toward photochromic and long-persistent photoluminescent smart windows

Salhah D. Al-Qahtani, Adel M. Binyaseen, Enas Aljuhani, Meshari Aljohani, Hanan K. Alzahrani, Reem Shah, Nashwa M. El-Metwaly

Summary: Novel fluorescent coatings developed for glass materials, including photochromic fluorescent and persistent phosphorescent coatings, display fluorescence and scratch-resistant superhydrophobic properties.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Achieving ultra-broadband electromagnetic wave absorption in high-entropy transition metal carbides (HE TMCs)

Weiming Zhang, Huimin Xiang, Fu-Zhi Dai, Biao Zhao, Shijiang Wu, Yanchun Zhou

Summary: This study aims to realize electromagnetic wave absorption materials with ultra-broadband absorption capacity and good stability by designing and synthesizing high-entropy transition metal carbides. The results show that excluding certain elements or introducing new elements can improve impedance matching and enhance absorption performance.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Realizing excellent energy storage properties in Na0.5Bi0.5TiO3-based lead-free relaxor ferroelectrics

Xu Li, Xiaoyan Dong, Fei Wang, Zhi Tan, Qiming Zhang, Hao Chen, Jingwen Xi, Jie Xing, Huanfu Zhou, Jianguo Zhu

Summary: In this study, the enhancement of energy storage properties in lead-free relaxor ferroelectrics was achieved through component regulation. The materials exhibited high recoverable energy storage density, large energy storage efficiency, and a wide operating temperature range. The excellent energy storage properties were mainly attributed to the suppression of early polarization saturation and the improvement of dielectric breakdown strength.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2022)

Article Materials Science, Ceramics

First-principles investigation of equilibrium phase, mechanical and thermodynamic properties of the Nowotny TM5Si3C ternary phase

Delin Pu, Yong Pan

Summary: The study investigates the structural stability, mechanical, and thermodynamic properties of TM5Si3C Nowotny phase using first-principles calculations. It is found that the four TM5Si3C ternary phases exhibit high thermal stability and good ductility, which is related to the vibration of the C atom in the system.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Composition optimization, high-temperature stability, and thermal cycling performance of Sc-doped Gd2Zr2O7 thermal barrier coatings: Theoretical and experimental studies

Lei Guo, Bowen Li, Yuxian Cheng, Lu Wang

Summary: In this study, Sc was doped into Gd2Zr2O7 to expand the potential for thermal barrier coating (TBC) applications. The solid solution mechanism of Sc in the lattice and the properties of the doped Gd2Zr2O7 were systematically studied. It was found that the optimal Sc doping content was 16.67 at% for achieving the best mechanical and thermophysical properties. The fabricated Gd-Sc/YSZ TBCs showed excellent phase and structural stability at high temperatures and exhibited outstanding thermal shock resistance.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

In-situ synthesis of ternary layered Y3Si2C2 ceramic on silicon carbide fiber for enhanced electromagnetic wave absorption

Wei Zhou, Yuting Zhang, Yang Li, Yanzi Gou, Xiaobing Zhou

Summary: A novel ternary layered ceramic of Y3Si2C2 was successfully synthesized on the surface of KD-SA SiC fiber for the first time, significantly improving the EMW absorption performance and achieving effective absorption bandwidth of 5.44 GHz.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Novel 3D grid porous Li4Ti5O12 thick electrodes fabricated by 3D printing for high performance lithium-ion batteries

Changyong Liu, Yin Qiu, Yanliang Liu, Kun Xu, Ning Zhao, Changshi Lao, Jun Shen, Zhangwei Chen

Summary: This study investigates the effects of various electrode parameters on electrochemical performance, aiming to bridge the gap between 3D printed electrode design and performance. Fabricated using low temperature direct writing technology, the 3D grid porous Li4Ti5O12 thick electrodes demonstrate impressive electrochemical performance.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Effects of carbon nanomaterials and MXene addition on the performance of nitrogen doped MnO2 based supercapacitors

Hilal Pecenek, Sevda Yetiman, Fatma Kilic Dokan, M. Serdar Onses, Erkan Yilmaz, Ertugrul Sahmetlioglu

Summary: This study investigates the effect of carbon nanomaterials and MXene addition on MnO2 based supercapacitor electrodes, and finds that MXene based composite materials exhibit the highest specific capacitance and exceptional cycling efficiency. The favorable interaction between MnO2 and nanoscale materials enhances conductivity and surface area, leading to superior supercapacitor efficiency.

CERAMICS INTERNATIONAL (2022)

Article Materials Science, Ceramics

Remarkably enhanced piezo-photocatalytic performance in BaTiO3/CuO heterostructures for organic pollutant degradation

Chengye Yu, Mengxi Tan, Chengdong Tao, Yuxuan Hou, Chuanbao Liu, Huimin Meng, Yanjing Su, Lijie Qiao, Yang Bai

Summary: Introducing polarization field is an effective strategy to enhance photocatalytic performance. A new type of BaTiO3/CuO heterostructure catalyst was designed and synthesized in this study, achieving high piezo-photocatalytic activity through the synergy of heterojunction and piezoelectric effect. The BaTiO3/CuO heterostructure showed significantly enhanced piezo-photocatalytic degradation efficiency of organic pollutants.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Porous, multi-layered piezoelectric composites based on highly oriented PZT/PVDF electrospinning fibers for high-performance piezoelectric nanogenerators

Xiangxin Du, Zheng Zhou, Zhao Zhang, Liqin Yao, Qilong Zhang, Hui Yang

Summary: This study demonstrates the potential application of multi-layered piezoelectric fiber composites in flexible energy harvesting devices. The porous structure effectively enhances the overall polarization and surface bound charge density, resulting in a highly efficient electromechanical conversion. The PENG based on the composite fibers shows higher sensitivity and excellent flexibility compared to PENGs with other porous structures.

JOURNAL OF ADVANCED CERAMICS (2022)

Article Materials Science, Ceramics

Nanocrystalline high-entropy carbide ceramics with improved mechanical properties

Mengdong Ma, Yanan Sun, Yingju Wu, Zhisheng Zhao, Li Ye, Yanhui Chu

Summary: Nanocrystalline (Hf0.25Zr0.25Ta0.25Ti0.25)C high-entropy carbide ceramics were successfully prepared through high-pressure sintering, showing improved mechanical properties at 1600 degrees C. Furthermore, the high-temperature Vickers hardness exhibited a linear decrease, influenced by the ZrO2 impurity phase at grain boundaries and the softening effect at elevated temperatures.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Materials Science, Ceramics

Design of Ti4+-doped Li3V2(PO4)3/C fibers for lithium energy storage

Zan Huang, Peifang Luo, Honghong Zheng

Summary: In this work, a facile method was proposed to fabricate Ti4+-doped Li3V2(PO4)3/C nanofibers, and the Ti4+ doping contributed to the improved electrical conductivity and Li+ diffusion coefficient, resulting in good battery characteristics.

CERAMICS INTERNATIONAL (2022)