Engineering, Chemical

Article Engineering, Environmental

Rationally designed Ti3C2 MXene@TiO2/CuInS2 Schottky/S-scheme integrated heterojunction for enhanced photocatalytic hydrogen evolution

Wenxiang Yang, Guozhi Ma, Yin Fu, Ke Peng, Hongli Yang, Xiaoqiang Zhan, Weiyou Yang, Lin Wang, Huilin Hou

Summary: The construction of Ti3C2 MXene@TiO2/CuInS2 heterojunction photocatalysts by a two-step hydrothermal process enhances the photocatalytic hydrogen generation activity. The synergistic effects of the hybrid photocatalysts result in improved visible-light harvesting, charge transfer, and active site for H-2 evolution, demonstrating their potential applications in this field.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Applied

Status and challenges facing representative anode materials for rechargeable lithium batteries

Liqiang Zhang, Chenxi Zhu, Sicheng Yu, Daohan Ge, Haoshen Zhou

Summary: This review discusses four representative anode materials for rechargeable lithium batteries, detailing their characteristics and challenges. It also summarizes recent advances, primarily focusing on modification strategies of anode materials and optimization of the electrode/electrolyte interface.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Engineering, Environmental

Self-cleaning photocatalytic MXene composite membrane for synergistically enhanced water treatment: Oil/water separation and dyes removal

Qingquan Lin, Guangyong Zeng, Guilong Yan, Jianquan Luo, Xiaojie Cheng, Ziyan Zhao, Han Li

Summary: A novel two-dimensional Bi2O2CO3@MXene photocatalytic composite membrane was reported for water treatment, showing excellent multifunctional abilities including high water flux, high rejection ratio for oil/water emulsions, and efficient dye removal. This composite membrane also maintained stable permeability and selectivity after five consecutive cycles with visible light irradiation. Mechanisms for the improvement of photocatalytic activity and membrane permeability were revealed through density functional theory (DFT) calculation and Finite Element Method (FEM) analysis.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Insights into the synergistic role of photocatalytic activation of peroxymonosulfate by UVA-LED irradiation over CoFe2O4-rGO nanocomposite towards effective Bisphenol A degradation: Performance, mineralization, and activation mechanism

Aydin Hassani, Paria Eghbali, Fayyaz Mahdipour, Stanislaw Waclawek, Kun-Yi Andrew Lin, Farshid Ghanbari

Summary: In this study, a CFO-rGO nanocomposite was synthesized and used to activate PMS under UVA-LED irradiation for BPA treatment. The CFO-rGO was characterized by various analytical techniques and its performance, operating factors, reactive species, and mechanism were investigated. The results showed that CFO-rGO exhibited efficient degradation of BPA under mild conditions, with high potential for recyclability and stability.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Multidisciplinary

Carrier grain boundary scattering in thermoelectric materials

Chaoliang Hu, Kaiyang Xia, Chenguang Fu, Xinbing Zhao, Tiejun Zhu

Summary: Bulk nanostructuring has been a leading strategy for optimizing thermoelectric properties by introducing strong grain boundary scattering, but recent findings have shown that charge carrier transport in some nanostructured materials can be significantly suppressed. Understanding the interaction mechanism of grain boundaries on carrier transport and strategies to enhance thermoelectric performance are crucial. Additionally, using the charge shielding ratio as an indicator to distinguish between different scattering mechanisms is proposed.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Physical

Self-supported bimetallic phosphides with artificial heterointerfaces for enhanced electrochemical water splitting

Shuang Yang, Ji-Yu Zhu, Xiao-Nan Chen, Meng-Jie Huang, Sheng-Hao Cai, Ji-Yuan Han, Ji-Sen Li

Summary: In this study, a new catalyst Ni2P-Ru2P/NF was reported, which showed excellent electrocatalytic performance for the oxygen and hydrogen evolution reactions in alkaline media. Additionally, it demonstrated fast catalytic performance for full water splitting with a low cell voltage.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

Phase change material microcapsules with melamine resin shell via cellulose nanocrystal stabilized Pickering emulsion in-situ polymerization

Zhe Zhang, Zhen Zhang, Tian Chang, Juan Wang, Xin Wang, Guofu Zhou

Summary: PCM microcapsules with MF shell were successfully prepared with CNCs as emulsifiers, achieving stable encapsulation of PCMs and enhanced heat conduction efficiency.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Multidisciplinary

Tissue-derived carbon microbelt paper: a high-initial-coulombic-efficiency and low-discharge-platform K+-storage anode for 4.5 V hybrid capacitors

Taoqiu Zhang, Zhiefei Mao, Xiaojun Shi, Jun Jin, Beibei He, Rui Wang, Yansheng Gong, Huanwen Wang

Summary: Hard carbon microbelt paper (HCMB) prepared from cheap and renewable sanitary tissue as a binder-free anode exhibits high initial coulombic efficiency, excellent rate capability, and superior cycling stability. HCMB-based anodes demonstrate low discharge platform similar to graphite, suitable for potassium ion capacitors. Additionally, the effect of carbonization temperature on the K+-storage behavior of HCMB is systematically investigated and compared with graphite and soft carbon counterparts.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Optimized carrier extraction at interfaces for 23.6% efficient tin-lead perovskite solar cells

Shuaifeng Hu, Kento Otsuka, Richard Murdey, Tomoya Nakamura, Minh Anh Truong, Takumi Yamada, Taketo Handa, Kazuhiro Matsuda, Kyohei Nakano, Atsushi Sato, Kazuhiro Marumoto, Keisuke Tajima, Yoshihiko Kanemitsu, Atsushi Wakamiya

Summary: In this study, carrier extraction in mixed tin-lead perovskite solar cells is improved by modifying the surfaces with ethylenediammonium diiodide and glycine hydrochloride. The modified solar cells show improved performance and stability, with efficiencies of up to 23.6% and retaining over 80% of initial efficiency after 200 hours of continuous operation.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Physical

Synthesis of acidic MIL-125 from plastic waste: Significant contribution of N orbital for efficient photocatalytic degradation of chlorobenzene and toluene

Xiaodong Zhang, Ke Yue, Renzhi Rao, Jinfeng Chen, Qiang Liu, Yang Yang, Fukun Bi, Yuxin Wang, Jingcheng Xu, Ning Liu

Summary: In this study, we synthesized MIL-125 using plastic-based terephthalic acid and modified it with amino and nitro groups. The results showed that amino modification promoted the visible absorption range and acidity of MIL-125, leading to efficient catalytic degradation of chlorobenzene and toluene.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Review Chemistry, Applied

Layered double hydroxide (LDH)-based materials: A mini-review on strategies to improve the performance for photocatalytic water splitting

Hanane Boumeriame, Eliana S. Da Silva, Alexey S. Cherevan, Tarik Chafik, Joaquim L. Faria, Dominik Eder

Summary: This review discusses the latest research on the use of LDH materials for photocatalytic water-splitting applications, highlighting synthetic strategies and post-modifications to improve their performance. By selecting appropriate experimental conditions, it is possible to significantly enhance the photoactivity of LDH and modified LDH-based materials.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Energy & Fuels

Bioenergy and bio-products from bio-waste and its associated modern circular economy: Current research trends, challenges, and future outlooks

Archana Jain, Surendra Sarsaiya, Mukesh Kumar Awasthi, Ranjan Singh, Rishabh Rajput, Umesh C. Mishra, Jishuang Chen, Jingshan Shi

Summary: The integration of biowaste into cutting-edge circular economy can greatly increase the production of sustainable bioproducts and bioenergy. Utilizing microbial analysis, valuable bioenergy and bioproduct aspirations can be transformed into practical mechanical bioproducts, highlighting the impact of bioeconomy across various sectors.
Article Thermodynamics

Insight into biomass pyrolysis mechanism based on cellulose, hemicellulose, and lignin: Evolution of volatiles and kinetics, elucidation of reaction pathways, and characterization of gas, biochar and bio-oil

Dengyu Chen, Kehui Cen, Xiaozhuang Zhuang, Ziyu Gan, Jianbin Zhou, Yimeng Zhang, Hong Zhang

Summary: This study investigated the pyrolysis behavior and product of the three major components of biomass. The results showed that their characteristics and thermal stability were related to their unique chemical structures. Different volatiles were generated during pyrolysis, and the thermal decomposition pathways of cellulose, hemicellulose, and lignin were proposed.

COMBUSTION AND FLAME (2022)

Article Energy & Fuels

Glass/Caryota urens hybridized fibre-reinforced nanoclay/SiC toughened epoxy hybrid composite: mechanical, drop load impact, hydrophobicity and fatigue behaviour

P. Raju, K. Raja, K. Lingadurai, T. Maridurai, S. C. Prasanna

Summary: In this study, a natural fiber-based polymer matrix composite was prepared and investigated. Glass-Caryota urens hybrid fiber was used as the primary reinforcement, and nanoclay and SiC were added to improve the toughness of the epoxy resin matrix. The results showed that the addition of nanoclay and SiC improved the mechanical properties and fatigue life cycle of the composite material. The hybrid fiber epoxy composites with improved properties could be widely used in engineering applications.

BIOMASS CONVERSION AND BIOREFINERY (2023)

Article Engineering, Environmental

Conductive PEDOT:PSS/cellulose nanofibril paper electrodes for flexible supercapacitors with superior areal capacitance and cycling stability

Haishun Du, Miaomiao Zhang, Kun Liu, Mahesh Parit, Zhihua Jiang, Xinyu Zhang, Bin Li, Chuanling Si

Summary: In this study, mechanically strong and conductive PEDOT:PSS based bulk films were successfully prepared using Cellulose nanofibrils (CNF) as building blocks. The optimized PEDOT:PSS/CNP exhibited excellent flexibility, high tensile strength (72 MPa), and high electrical conductivity (66.67 S/cm), making it a promising electrode material for flexible supercapacitors. The symmetric supercapacitor assembled using PEDOT:PSS/CNP showed outstanding electrochemical performance with high specific capacitance and energy density, as well as remarkable cycling stability.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Highly efficient photothermal catalysis of toluene over Co3O4/TiO2 p-n heterojunction: The crucial roles of interface defects and band structure

Yang Yang, Shenghao Zhao, Fukun Bi, Jinfeng Chen, Yuxin Wang, Lifeng Cui, Jingcheng Xu, Xiaodong Zhang

Summary: The unique properties presented in the interface of composite oxides have important implications for catalytic degradation. In this study, MOx/TiO2 composites were used for the full spectrum light-assisted photothermal catalytic degradation of toluene. A p-n heterojunction with interface defects was constructed between TiO2 and Co3O4, leading to improved photothermal performance. The relationship between interface properties, band structure, and catalytic performance was comprehensively studied based on experimental results and theoretical calculations.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

Mesoporous black TiO2/MoS2/Cu2S hierarchical tandem heterojunctions toward optimized photothermal-photocatalytic fuel production

Zhenzi Li, Haoze Li, Shijie Wang, Fan Yang, Wei Zhou

Summary: Mesoporous black TiO2/MoS2/Cu2S hierarchical tandem heterojunctions are fabricated as photocatalysts with visible-light photocatalytic hydrogen production rate of 3376.7 μmol h-1 g-1, attributed to suitable band gap alignment in the hierarchical tandem heterojunctions.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Thermodynamics

Laser processing of graphene and related materials for energy storage: State of the art and future prospects

Rajesh Kumar, Angel Perez del Pino, Sumanta Sahoo, Rajesh Kumar Singh, Wai Kian Tan, Kamal K. Kar, Atsunori Matsuda, Ednan Joanni

Summary: This review summarizes recent studies on laser-assisted synthesis and modification of graphene-based materials, as well as their application as electrodes for supercapacitors and batteries. It provides an overview of the physical properties of graphene and different types of laser processing operations, with a detailed discussion on the practical uses of laser techniques for fabricating electrode materials.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2022)

Article Engineering, Environmental

Bimetallic CoFe-MOF@Ti3C2Tx MXene derived composites for broadband microwave absorption

Fu Chen, Shanshan Zhang, Beibei Ma, Yao Xiong, Hui Luo, Yongzhi Cheng, Xiangcheng Li, Xian Wang, Rongzhou Gong

Summary: In this study, bimetallic CoFe-MOF@Ti3C2Tx MXene derived multiple-interfacial composites with controllable structures were prepared and their microwave absorption properties were investigated. The results show that the synthesized composite exhibits excellent microwave absorption performance, providing a new approach for the design of high-performance microwave absorbing materials.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

S-scheme MIL-101(Fe) octahedrons modified Bi2WO6 microspheres for photocatalytic decontamination of Cr(VI) and tetracycline hydrochloride: Synergistic insights, reaction pathways, and toxicity analysis

Shijie Li, Chunchun Wang, Yanping Liu, Yazi Liu, Mingjie Cai, Wei Zhao, Xiaoguang Duan

Summary: Solar-driven elimination of refractory contaminants is an ideal approach for environmental remediation. However, the photocatalytic performance of photocatalysts is limited by insufficient reactive sites and fast recombination of electrons and holes. In this study, a novel metal-organic framework-based heterostructure of MIL-101(Fe)/Bi2WO6 was synthesized, which exhibited significantly enhanced photoactivity for Cr(VI) reduction and tetracycline hydrochloride oxidation compared to individual Bi2WO6 and MIL-101(Fe). The improved catalytic performance can be attributed to the enlarged surface area and pollutant adsorption facilitated by MIL-101(Fe), as well as the efficient photo-carrier transport mechanism supported by oxygen vacancies.

CHEMICAL ENGINEERING JOURNAL (2023)