Engineering, Chemical

Article Engineering, Environmental

Facile fabrication of TaON/Bi2MoO6 core-shell S-scheme heterojunction nanofibers for boosting visible-light catalytic levofloxacin degradation and Cr(VI) reduction

Shijie Li, Chunchun Wang, Mingjie Cai, Fang Yang, Yanping Liu, Jialin Chen, Peng Zhang, Xin Li, Xiaobo Chen

Summary: The study developed a novel TaON/Bi2MoO6 S-scheme heterojunction photocatalyst with a core-shell fiber-shaped structure, demonstrating high catalytic activity towards levofloxacin antibiotic degradation and Cr(VI) reduction. The material showed excellent stability and reusability, and a possible photocatalytic reaction mechanism for removal of LEV and Cr(VI) was proposed, providing insights for fabricating efficient water purification photocatalysts.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Applied

A review on heterogeneous photocatalysis for environmental remediation: From semiconductors to modification strategies

Huijie Wang, Xin Li, Xiaoxue Zhao, Chunyan Li, Xianghai Song, Peng Zhang, Pengwei Huo, Xin Li

Summary: Heterogeneous photocatalysis has potential applications in environmental remediation, but faces challenges such as low efficiency and high costs. More research is needed to better understand and apply it in practical scenarios. This review provides reference directions for designing photocatalytic systems for environmental pollutants.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Chemistry, Multidisciplinary

Manipulating the D:A interfacial energetics and intermolecular packing for 19.2% efficiency organic photovoltaics

Chengliang He, Youwen Pan, Yanni Ouyang, Qing Shen, Yuan Gao, Kangrong Yan, Jin Fang, Yiyao Chen, Chang-Qi Ma, Jie Min, Chunfeng Zhang, Lijian Zuo, Hongzheng Chen

Summary: Manipulating the donor:acceptor energetics is crucial for achieving balanced charge separation and recombination in organic solar cells (OSCs). In this study, a non-fullerene electron acceptor, BTP-H2, was designed and synthesized to pair with the polymer donor PM6, showing strong intermolecular interaction and near-zero highest occupied molecular orbital (HOMO) offset. The results demonstrated efficient charge separation and optimized energy conversion, leading to high-performance OSCs with a power conversion efficiency (PCE) of 18.5% and a peak photon-to-electron response of approximately 90%.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Engineering, Environmental

Photocatalytic degradation of tetracycline antibiotic by a novel Bi2Sn2O7/Bi2MoO6 S-scheme heterojunction: Performance, mechanism insight and toxicity assessment

Shijie Li, Chunchun Wang, Yanping Liu, Mingjie Cai, Yaning Wang, Huiqiu Zhang, Yang Guo, Wei Zhao, Zhaohui Wang, Xiaobo Chen

Summary: Novel Bi2Sn2O7/Bi2MoO6 step-scheme heterojunctions were fabricated, which could effectively degrade tetracycline antibiotics and showed no toxicity.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Chemistry, Multidisciplinary

Strategies of regulating Zn2+ solvation structures for dendrite-free and side reaction-suppressed zinc-ion batteries

Jin Cao, Dongdong Zhang, Xinyu Zhang, Zhiyuan Zeng, Jiaqian Qin, Yunhui Huang

Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Applied

Integration of 2D layered CdS/WO3 S-scheme heterojunctions and metallic Ti3C2 MXene-based Ohmic junctions for effective photocatalytic H2 generation

Junxian Bai, Rongchen Shen, Zhimin Jiang, Peng Zhang, Youji Li, Xin Li

Summary: A 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces was designed and constructed, which effectively promoted spatially directional charge separation and transport between CdS and WO3 nanosheets, resulting in an increased visible-light hydrogen evolution rate.

CHINESE JOURNAL OF CATALYSIS (2022)

Review Chemistry, Multidisciplinary

Solar fuels: research and development strategies to accelerate photocatalytic CO2 conversion into hydrocarbon fuels

Eunhee Gong, Shahzad Ali, Chaitanya B. Hiragond, Hong Soo Kim, Niket S. Powar, Dongyun Kim, Hwapyong Kim, Su-Il In

Summary: This review highlights recent advances, challenges, and potential solutions in photocatalytic production of solar fuels from CO2, including discussions on various catalysts and reaction mechanisms.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Application of MOFs and COFs for photocatalysis in CO2 reduction, H2 generation, and environmental treatment

Yifeng Zhang, Hangxi Liu, Feixue Gao, Xiaoli Tan, Yawen Cai, Baowei Hu, Qifei Huang, Ming Fang, Xiangke Wang

Summary: MOFs and COFs, as important photocatalytic materials, have high physical/chemical stability and structural diversity, and are widely used in CO2 reduction, H2 generation, and environmental pollution treatment. By summarizing the methods and mechanisms to improve their photocatalytic performance, the development of the photocatalysis field is expected to be further promoted.

ENERGYCHEM (2022)

Article Chemistry, Applied

S-Scheme photocatalyst TaON/Bi2WO6 nanofibers with oxygen vacancies for efficient abatement of antibiotics and Cr(VI): Intermediate eco-toxicity analysis and mechanistic insights

Shijie Li, Mingjie Cai, Yanping Liu, Chunchun Wang, Kangle Lv, Xiaobo Chen

Summary: In this study, a novel TaON/Bi2WO6 S-scheme heterojunction nanofibers were developed, showing exceptional visible-light photocatalytic performance for pollutant degradation with satisfactory stability. The research provides guidance for designing high-performance photocatalysts with defects for environmental protection.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Energy & Fuels

Understanding farmers' intention and willingness to install renewable energy technology: A solution to reduce the environmental emissions of agriculture

Ehsan Elahi, Zainab Khalid, Zhixin Zhang

Summary: This study examines the social acceptance of PV water pumps and the willingness of farmers in rural Pakistan to pay extra for green electricity. The findings suggest that farmers' intentions to install PV water pumps are positively related to attitudes towards environmental protection, subjective norms of sustainable behavior, lack of electricity access, perceived behavior control, and relative advantages. However, the cost of the PV water pump has a negative impact on farmers' installation intentions. The probability of being willing to pay extra for green electricity is influenced by education, household income, lack of access to grid electricity, age, and the cost of green energy technology.

APPLIED ENERGY (2022)

Article Chemistry, Multidisciplinary

Unraveling the dual defect sites in graphite carbon nitride for ultra-high photocatalytic H2O2 evolution

Xu Zhang, Peijie Ma, Cong Wang, Liyong Gan, Xianjie Chen, Peng Zhang, Yang Wang, Hui Li, Lihua Wang, Xiaoyuan Zhou, Kun Zheng

Summary: Defect engineering modified graphite carbon nitride (g-C3N4) with dual defect sites, -C N groups and N vacancies, has been found to significantly enhance the photocatalytic production of H2O2. The dual defect sites form an electron-rich structure and lead to a more localized charge density distribution, which improves light absorption, carrier separation, selectivity, and activity of H2O2 generation. The N vacancies effectively adsorb and activate O-2, while the -C N groups facilitate the adsorption of H+, synergistically promoting H2O2 generation. The modified g-C3N4 achieved a high H2O2 generation rate and apparent quantum efficiency, surpassing previously reported g-C3N4-based photocatalysts.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Review Engineering, Environmental

Battery thermal management systems (BTMs) based on phase change material (PCM): A comprehensive review

Jie Luo, Deqiu Zou, Yinshuang Wang, Shuo Wang, Li Huang

Summary: This paper introduces the advantages of battery thermal management system based on phase change materials, analyzes the performance of different systems, and discusses future research directions.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Amorphous type FeOOH modified defective BiVO4 photoanodes for photoelectrochemical water oxidation

Xinyu Lu, Kai-hang Ye, Siqi Zhang, Jingnan Zhang, Jindong Yang, Yongchao Huang, Hongbing Ji

Summary: A new method was designed to induce oxygen vacancies in BiVO4/FeOOH nanostructures, leading to improved performance in photoelectrochemical water oxidation. The strategy involved integrating Bi2S3 quantum dots into BiVO4/FeOOH to create defect-rich high-performance photoanode Vo-BiVO4/FeOOH.

CHEMICAL ENGINEERING JOURNAL (2022)

Review Engineering, Environmental

Advanced oxidation processes (AOPs) based wastewater treatment - unexpected nitration side reactions-a serious environmental issue: A review

Manoj P. Rayaroth, Charuvila T. Aravindakumar, Noor S. Shah, Grzegorz Boczkaj

Summary: This paper focuses on the formation of nitro-products in wastewater treatment processes and compares the mechanisms of various AOPs. Increased attention should be given to monitoring and minimizing the formation of nitro-products during oxidative degradation processes.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Energy & Fuels

Global low-carbon energy transition in the post-COVID-19 era

Jinfang Tian, Longguang Yu, Rui Xue, Shan Zhuang, Yuli Shan

Summary: The COVID-19 pandemic poses significant challenges for energy transition, but also presents opportunities. This study provides a comprehensive analysis of the dynamics between energy transition and COVID-19 globally and proposes a low-carbon energy transition roadmap for the post-pandemic era.

APPLIED ENERGY (2022)

Article Chemistry, Physical

In situ construction of S-scheme AgBr/BiOBr heterojunction with surface oxygen vacancy for boosting photocatalytic CO2 reduction with H2O

Zerui Miao, Qingli Wang, Yanfeng Zhang, Lingpeng Meng, Xuxu Wang

Summary: In this study, an AgBr/BiOBr heterojunction with surface oxygen vacancies was synthesized using a simple chemical method, which showed significantly improved photoreduction rates of CO2 compared to pure BiOBr. The unique S-scheme band structure and oxygen vacancies were found to enhance the utilization of sunlight and increase the separation and transfer of photogenerated charge carriers, leading to efficient photocatalytic reduction of CO2.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Photo-Fenton degradation of tetracycline over Z-scheme Fe-g-C3N4/Bi2WO6 heterojunctions: Mechanism insight, degradation pathways and DFT calculation

Caihua Liu, Hongling Dai, Chaoqun Tan, Qianyu Pan, Fengping Hu, Xiaoming Peng

Summary: In this study, a Fe-g-C3N4/Bi2WO6 Z-scheme heterojunction was elaborately designed for the degradation of tetracycline (TC). The performance of H2O2 decomposition in the Z-scheme heterojunction was improved by the doping of iron, enhancing the transportability of photogenerated electrons and facilitating the spread of radicals. The study also found that O-1(2) and center dot O-2- were the main active species participating in the degradation process, according to efficacy analyses and experimental results.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Chemical

Novel Cd0.5Zn0.5S/Bi2MoO6 S-scheme heterojunction for boosting the photodegradation of antibiotic enrofloxacin: Degradation pathway, mechanism and toxicity assessment

Mingjie Cai, Yanping Liu, Chunchun Wang, Wei Lin, Shijie Li

Summary: The artificial S-scheme photocatalysis system, mimicking natural photosynthesis, has shown excellent potential for the photocatalytic degradation of pharmaceuticals and personal care products (PPCPs). In this study, Cd0.5Zn0.5S/Bi2MoO6 S-scheme heterostructures were fabricated and showed significantly improved degradation efficiency of enrofloxacin compared to Cd0.5Zn0.5S and Bi2MoO6 alone. The integration of Cd0.5Zn0.5S with Bi2MoO6 resulted in effective spatial photo-carrier dissolution and optimized photo-redox capacity, leading to enhanced photocatalytic performance and stability. The study also revealed the toxicological analysis of intermediates and showcased the potential of the system for PPPCs degradation in authentic water systems.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Energy & Fuels

Mechanical, thermal and fatigue behaviour of surface-treated novelCaryota urensfibre-reinforced epoxy composite

V. R. Arun Prakash, J. Francis Xavier, G. Ramesh, T. Maridurai, K. Siva Kumar, R. Blessing Sam Raj

Summary: By treatingCaryota urensnatural fibres with different surface treatments, the mechanical, thermal and fatigue properties of the epoxy biocomposites can be improved. In particular, the silane treatment shows the best performance in terms of tensile, flexural and impact properties, as well as the highest fatigue life.

BIOMASS CONVERSION AND BIOREFINERY (2022)

Article Engineering, Environmental

Activation of peroxymonosulfate by single-atom Fe-g-C3N4 catalysts for high efficiency degradation of tetracycline via nonradical pathways: Role of high-valent iron-oxo species and Fe-Nx sites

Xiaoming Peng, Jianqun Wu, Zilong Zhao, Xing Wang, Hongling Dai, Li Xu, Gaoping Xu, Yan Jian, Fengping Hu

Summary: A Fenton-like catalyst was prepared using isolated Fe single-atom and Fe clusters anchored onto a g-C3N4 framework for the heterogeneous activation of peroxymonosulfate (PMS) to degrade tetracycline (TC). The single Fe atoms served as active sites with optimal binding energy for PMS activation, leading to the production of high-valent iron-oxo species and single oxygen-dominated nonradical processes causing TC degradation. This study demonstrates the superior catalytic activity of single Fe atoms compared to Fe clusters in the activation of PMS for TC degradation.

CHEMICAL ENGINEERING JOURNAL (2022)