Chemistry, Physical

Review Chemistry, Physical

Recycling of Lithium-Ion Batteries-Current State of the Art, Circular Economy, and Next Generation Recycling

Jonas Neumann, Martina Petranikova, Marcel Meeus, Jorge D. Gamarra, Reza Younesi, Martin Winter, Sascha Nowak

Summary: This paper provides an overview of the current state and future trends in the recycling technology of lithium-ion batteries. The widespread use of lithium-ion batteries in various applications necessitates the development of efficient recycling methods. However, the complexity of these batteries and their varying compositions pose challenges in establishing a robust recycling procedure. The paper discusses current practices and regulations, as well as predictions and approaches for future battery recycling.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Multidisciplinary

Biomimetic Nanoerythrosome-Coated Aptamer-DNA Tetrahedron/Maytansine Conjugates: pH-Responsive and Targeted Cytotoxicity for HER2-Positive Breast Cancer

Wenjuan Ma, Yuting Yang, Jianwei Zhu, Weiqiang Jia, Tao Zhang, Zhiqiang Liu, Xingyu Chen, Yunfeng Lin

Summary: DNA materials have been used as nanocarriers for targeted cancer therapy, but their short half-life and low bioavailability hinder their clinical translation. This study developed a HER2-targeted DNA-aptamer-modified DNA tetrahedron/DM1 conjugate, and applied a biomimetic camouflage to enhance drug delivery and tumor-stimulated drug release. The hybrid erythrosome-based nanoparticles exhibited superior inhibition of HER2-positive cancer.

ADVANCED MATERIALS (2022)

Review Chemistry, Multidisciplinary

Development of Conductive Hydrogels for Fabricating Flexible Strain Sensors

Gang Li, Chenglong Li, Guodong Li, Dehai Yu, Zhaoping Song, Huili Wang, Xiaona Liu, Hong Liu, Wenxia Liu

Summary: Conductive hydrogels, incorporating various conductive materials into polymeric network hydrogels, have been developed for strain sensors with unique properties such as electrical conductivity, mechanical properties, self-healing, and anti-freezing properties. These properties allow conductive hydrogel-based strain sensors to exhibit excellent performance in identifying external stimuli and detecting human body movement, even at subzero temperatures.
Article Chemistry, Multidisciplinary

Over 21% Efficiency Stable 2D Perovskite Solar Cells

Ming Shao, Tong Bie, Lvpeng Yang, Yerun Gao, Xing Jin, Feng He, Nan Zheng, Yu Yu, Xinliang Zhang

Summary: This study fabricated 2D perovskite solar cells incorporating FA, MA, and FA/MA, resulting in significantly enhanced light absorption and device stability. The introduction of FA cations increased the 3D-like phase relative to 2D phases and effectively suppressed the formation of the yellow delta phase.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

A Multifunctional Flexible Composite Film with Excellent Multi-Source Driven Thermal Management, Electromagnetic Interference Shielding, and Fire Safety Performance, Inspired by a Brick-Mortar Sandwich Structure

Shang Gong, Xinxin Sheng, Xiaolong Li, Mengjie Sheng, Hao Wu, Xiang Lu, Jinping Qu

Summary: This paper presents a method for fabricating a multifunctional composite film with excellent thermal management capability, EMI shielding effectiveness, and fire safety performance. The film possesses multiple-source driven thermal management capability and high EMI shielding effectiveness, along with good flexibility and high enthalpy. The outstanding performance of the film offers broad application prospects in wearable products.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Physical

Quantum computational, spectroscopic investigations on N-(2-((2-chloro-4,5-dicyanophenyl)amino)ethyl)-4-methylbenzenesulfonamide by DFT/TD-DFT with different solvents, molecular docking and drug-likeness researches

Necmi Dege, Halil Gokce, Onur Erman Dogan, Gokhan Alpaslan, Tuggan Agar, S. Muthu, Yusuf Sert

Summary: The experimental and theoretical research on the molecule N-(2-((2-chloro-4,5-dicyanophenyl)amino)ethyl)-4-methylbenzenesulfonamide was conducted in this study. The study involved various spectroscopic techniques and computational methods to analyze the molecular properties and drug-likeness.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2022)

Review Chemistry, Physical

Liquid electrolyte: The nexus of practical lithium metal batteries

Hansen Wang, Zhiao Yu, Xian Kong, Sang Cheol Kim, David T. Boyle, Jian Qin, Zhenan Bao, Yi Cui

Summary: The specific energy of commercial lithium-ion batteries is approaching the theoretical limit. The development of high energy density Li metal batteries is needed for future consumer electronics and electric vehicle markets. Electrolyte engineering can address the issues associated with Li metal batteries, but there are still gaps between the performance of current Li metal batteries and commercial requirements. Further improvements require systematic analysis of existing electrolyte design methodologies.
Review Chemistry, Applied

Advances and prospects of PVDF based polymer electrolytes

Yixin Wu, Yu Li, Yang Wang, Qian Liu, Qingguo Chen, Minghua Chen

Summary: Developing highly foldable batteries with no safety hazard is crucial for portable, wearable, and implantable electric devices. Solid-state batteries, particularly those based on PVDF electrolytes, show great potential, but also face challenges such as lower ionic conductivity and lack of reactive groups. Recent research has focused on gel polymer electrolytes and all solid polymer electrolytes based on PVDF to address these issues.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

Construction of 1D/2D W18O49/Porous g-C3N4 S-Scheme Heterojunction with Enhanced Photocatalytic H2 Evolution

Yue Huang, Feifei Mei, Jinfeng Zhang, Kai Dai, Graham Dawson

Summary: Photocatalytic hydrogen production is an effective strategy for converting solar energy into chemical energy. This study explores the use of a suitable heterojunction to improve the performance of photocatalytic H-2 production. By synthesizing 2D porous carbon nitride (PCN) and growing 1D WO on PCN, a step-scheme (S-scheme) heterojunction is achieved. The results show that the 20%WO/PCN composite has a higher H-2 production rate.

ACTA PHYSICO-CHIMICA SINICA (2022)

Article Chemistry, Multidisciplinary

Stretchable Triboelectric Self-Powered Sweat Sensor Fabricated from Self-Healing Nanocellulose Hydrogels

Ying Qin, Jilong Mo, Yanhua Liu, Song Zhang, Jinlong Wang, Qiu Fu, Shuangfei Wang, Shuangxi Nie

Summary: This article introduces a fully flexible self-powered sweat sensor fabricated from a cellulose-based conductive hydrogel. The sweat sensor has high flexibility, stability, and analytical sensitivity, and can analyze perspiration constituents in real time and wirelessly transmit the results to a user interface.

ADVANCED FUNCTIONAL MATERIALS (2022)

Editorial Material Chemistry, Physical

Soft Shorts Hidden in Zinc Metal Anode Research

Qing Li, Ao Chen, Donghong Wang, Zengxia Pe, Chunyi Zhi

Article Chemistry, Multidisciplinary

Cation-Vacancy-Enriched Nickel Phosphide for Efficient Electrosynthesis of Hydrogen Peroxides

Zheng Zhou, Yuan Kong, Hao Tan, Qianwei Huang, Cheng Wang, Zengxia Pei, Haozhu Wang, Yangyang Liu, Yihan Wang, Sai Li, Xiaozhou Liao, Wensheng Yan, Shenlong Zhao

Summary: Electrocatalytic hydrogen peroxide synthesis via two-electron oxygen reduction reaction pathway is becoming increasingly important due to its green production process. Introducing cationic vacancies on nickel phosphide as a proof-of-concept to regulate the catalyst's properties has led to efficient H2O2 electrosynthesis. The created Ni cationic vacancies enriched Ni2-xP-V-Ni electrocatalyst exhibits remarkable 2e ORR performance and long-term durability, with optimized geometric and electronic structures. Cation vacancy engineering is believed to be an effective strategy for creating active heterogeneous catalysts with atomic precision.

ADVANCED MATERIALS (2022)

Review Chemistry, Physical

Recent progress on porous carbon and its derivatives from plants as advanced electrode materials for supercapacitors

Guosai Jiang, Raja Arumugam Senthil, Yanzhi Sun, Thangvelu Rajesh Kumar, Junqing Pan

Summary: Porous carbon materials, particularly derived from plants, have shown promising potential in energy storage due to their carbon-rich composition and unique channel structures. Research focuses on synthesis methods, multi-component carbon materials, and improving electrochemical performance, aiming to design electrode materials for efficient electrolyte ion and electron transport. Challenges and trends in utilizing plant-derived carbon materials for supercapacitor application are also highlighted.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Multidisciplinary

Encapsulation of Metallic Zn in a Hybrid MXene/Graphene Aerogel as a Stable Zn Anode for Foldable Zn-Ion Batteries

Jiahui Zhou, Man Xie, Feng Wu, Yang Mei, Yutong Hao, Li Li, Renjie Chen

Summary: The flexible MXene/graphene scaffold created through an oriented freezing process can effectively inhibit dendritic growth of the zinc-metal anode and form a solid electrolyte interface at the electrode/electrolyte interface, improving battery stability and cycling life.

ADVANCED MATERIALS (2022)

Article Chemistry, Multidisciplinary

Engineering Metallic Heterostructure Based on Ni3N and 2M-MoS2 for Alkaline Water Electrolysis with Industry-Compatible Current Density and Stability

Tong Wu, Erhong Song, Shaoning Zhang, Mengjia Luo, Chendong Zhao, Wei Zhao, Jianjun Liu, Fuqiang Huang

Summary: In this study, a novel metallic heterostructure was designed for efficient water electrolysis, achieving high stability and activity at large current density. The heterostructure overcame the issue of competitive adsorption by providing two separated reaction sites, and improved overall water splitting by regulating active electronic states through charge transfer.

ADVANCED MATERIALS (2022)

Review Chemistry, Multidisciplinary

Functionalizing Framework Nucleic-Acid-Based Nanostructures for Biomedical Application

Tao Zhang, Taoran Tian, Yunfeng Lin

Summary: This article discusses the strategies for functionalizing diverse tetrahedral framework nucleic acids (tFNAs) and their potential biomedical applications. tFNAs have the ability to scavenge reactive oxygen species, enhance cellular endocytosis and tissue permeability, and promote cell-material interactions. They can be used to treat inflammatory and degenerative diseases, and also have potential applications in targeted therapies, tissue regeneration, antitumor strategies, and antibacterial treatment through their structural programmability.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

Graphene aerogel-based NiAl-LDH/g-C3N4 with ultratight sheet-sheet heterojunction for excellent visible-light photocatalytic activity of CO2 reduction

Min Yang, Peng Wang, Youji Li, Senpei Tang, Xiao Lin, Haiyan Zhang, Zi Zhu, Feitai Chen

Summary: This article investigates the ultratight heterojunctions formed by NiAl-LDH/g-C3N4 nanosheets, which exhibit remarkable CO production rate under visible light irradiation, surpassing the conventional CO2 photocatalytic reduction efficiency. The unique structure promotes the transport and separation of carriers, providing new insights for designing photocatalysts with ideal CO2 reduction performance.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

High piezo/photocatalytic efficiency of Ag/Bi5O7I nanocomposite using mechanical and solar energy for N2 fixation and methyl orange degradation

Lu Chen, Wenqian Zhang, Junfeng Wang, Xiaojing Li, Yi Li, Xin Hu, Leihong Zhao, Ying Wu, Yiming He

Summary: In this work, an Ag/Bi5O7I nanocomposite was prepared and used for the piezo/photocatalytic reduction of N2 to NH3 and methyl orange degradation for the first time. The addition of Ag nanoparticles to the Bi5O7I nanorods enhanced the spatial separation of charge carriers and improved the catalytic performance. Under ultrasonic vibration, the optimal Ag/Bi5O7I catalyst exhibited high efficiency in MO degradation and piezocatalytic N2 fixation. Additionally, simultaneous ultrasonic vibration and light irradiation further improved the performance. However, the weak adhesion of Ag nanoparticles resulted in their detachment under long-term ultrasonic vibration, leading to a reduction in the catalytic performance.

GREEN ENERGY & ENVIRONMENT (2023)

Article Chemistry, Applied

Efficient photocatalytic hydrogen evolution over graphdiyne boosted with a cobalt sulfide formed S-scheme heterojunction

Zhiliang Jin, Hongying Li, Junke Li

Summary: Graphdiyne (GDY), a novel two-dimensional carbon hybrid material, has attracted significant attention due to its unique and excellent properties. This study reports new progress in the preparation of a composite material, Co9S8-GDY-CuI, using CuI powder as a catalytic material and a facile hydrothermal method. The Co9S8-GDY-CuI exhibited hydrogen production activity 10.29 times higher than that of pure GDY in the sensitization system. Characterization techniques provided evidence for the successful preparation of the material and its superior photocatalytic activity. A possible reaction mechanism and the effects of Co9S8 nanoparticles were also discussed.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Chemistry, Multidisciplinary

Synergy between Palladium Single Atoms and Nanoparticles via Hydrogen Spillover for Enhancing CO2 Photoreduction to CH4

Peigen Liu, Zixiang Huang, Xiaoping Gao, Xun Hong, Junfa Zhu, Gongming Wang, Yuen Wu, Jie Zeng, Xusheng Zheng

Summary: This study demonstrates the synergistic function between single Pd atoms and Pd nanoparticles on graphitic carbon nitride for selective photocatalytic reduction of CO2 into CH4, providing a new perspective for the development of selective photocatalytic CO2 conversion.

ADVANCED MATERIALS (2022)