Review
Chemistry, Inorganic & Nuclear
Sayed Y. Attia, Saad G. Mohamed, Yosry F. Barakat, Hamdy H. Hassan, Wail Al Zoubi
Summary: In recent years, Supercapacitors have gained significant attention and research as energy devices with outstanding cycling life, safe operation, low cost, and high power density. This review outlines the charge-storage mechanisms, scientific design principles, and important performance parameters of Supercapacitors, emphasizing the crucial role of electrode materials in their performance. Research progress on carbon-based materials, transition metal oxides, sulfides, hydroxides, MXenes, and metal nitrides is summarized, with a brief overview of the strategic direction for future growth in this field.
REVIEWS IN INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Shikha Gulati, Sneha Vijayan, Sanjay Kumar, Bharath Harikumar, Manoj Trivedi, Rajender S. Varma, Rajender S. Varma
Summary: This review discusses the application of metal-organic frameworks (MOFs)-based nanocatalysts for the direct conversion of carbon dioxide (CO2) into value-added chemicals. The unique features of MOFs, such as tunable porosity and high internal surface area, enable them to accelerate CO2 conversion reactions. This comprehensive review covers the recent trends and advancements in CO2 conversion using MOFs-based nanocatalysts, with a focus on the relationship between CO2 capture capacity and catalytic activity. The exceptional competence of these nanocomposites in CO2 conversion makes them promising candidates for real-world applications.
COORDINATION CHEMISTRY REVIEWS
(2023)
Review
Chemistry, Inorganic & Nuclear
Reddicherla Umapathi, Chikkili Venkateswara Raju, Seyed Majid Ghoreishian, Gokana Mohana Rani, Krishan Kumar, Mi-Hwa Oh, Jong Pil Park, Yun Suk Huh
Summary: Graphitic carbon nitride (GCN)-based nanostructures have shown promising applications in electrochemical detection of hazardous contaminants. However, a comprehensive analysis of recent research developments and the use of GCN-based sensing materials in electrochemical detection has not been fully explored. In this review, the synthesis, properties, and applications of GCN composites for the detection of hazardous contaminants were systematically analyzed and reviewed, providing insights into the immobilization methods, modification strategies, advantages, and disadvantages. The potential of GCN-based sensing materials for on-site electrochemical detection of hazardous contaminants and the advantages of on-site electrochemical sensing strategies and portable devices were emphasized.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Sevgi Kansiz, Arda Tolan, Mohammad Azam, Necmi Dege, Mahboob Alam, Yusuf Sert, Saud Al-Resayes, Hasan Icbudak
Summary: A novel acesulfame-based Co(II) complex with a square pyramidal geometry was synthesized and structurally elucidated. The solvatochromic characteristics and hydrogen bonding interactions in the crystal structure were investigated. The Hirshfeld surface analysis showed that hydrogen bonding was the most significant contribution to the crystal packing. Molecular docking simulations revealed the interaction between the complex and the CA IX receptor.
Article
Chemistry, Inorganic & Nuclear
Lin Yang, Zhong Zhang, Chaonan Zhang, Shuang Li, Guocheng Liu, Xiuli Wang
Summary: Reported a novel and efficient photocatalyst BHU-1, which can effectively decompose toxic substances and exhibits excellent catalytic performance under different light conditions. The evaluation of the treatment effect of various pollutants and the study of reaction mechanism demonstrated the potential application of BHU-1.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Yue Cao, Hongqian Gou, Pengfei Zhu, Zhiliang Jin
Summary: Reasonable design of heterojunction is crucial for enhancing the photocatalytic hydrogen evolution activity. In this study, a p-n heterojunction of 2D/3D structure was constructed using CoAl-LDH nanosheets and rock-like CuI. The introduction of CuI improved the dispersion of CoAl-LDH and provided more reaction sites for hydrogen evolution. The optical and electrochemical properties demonstrated that the p-n heterojunction promoted the separation and transfer of photon-generated carriers. The composite catalyst, CI-10, exhibited a significantly higher activity of 3.59 mmol g(-1) h(-1), which was 28.5 times higher than that of CuI. Furthermore, the influence of CuI dosage and pH value on the hydrogen evolution reaction was investigated, and a mechanism for the photocatalytic reaction of CI-10 was proposed.
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Chicheng Yan, Jiaqi Jin, Jieni Wang, Fangfang Zhang, Yijun Tian, Chenxiao Liu, Faqi Zhang, Leichang Cao, Yanmei Zhou, Qiuxia Han
Summary: Water pollution is a major cause of water shortage, and metal-organic frameworks (MOFs) show great potential in removing various pollutants from water due to their large specific surface area and controllability. This paper summarizes the adsorption and catalytic degradation mechanisms of MOFs for inorganic and emerging organic contaminants in water, discusses the best performing 3D-MOFs and MOF-based composites, and highlights the challenges and future prospects of using MOFs for water remediation.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Lin Tian, Xinle Pang, Hui Xu, Dongsheng Liu, Xinhua Lu, Jing Li, Ju Wang, Zhao Li
Summary: This study proposes a dual-doping strategy by doping Fe and S atoms to improve the electronic structure of CoP and enhance its electrocatalytic OER performance. By adjusting the carrier density and charge transfer characteristics, and utilizing the highly open nanobox structure to expose more active sites, excellent catalytic performance is achieved.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Elmehdi Moumen, Loubna Bazzi, Samir El Hankari
Summary: This article reviews the utilization of metal-organic frameworks (MOFs) in the adsorption and sensing of phosphate. MOFs, with their high surface area and tunability, have shown great potential in addressing environmental issues such as eutrophication. The article highlights the advantages and applications of different MOFs and their composites in phosphate adsorption and sensing, and compares them with existing adsorbents and sensors.
COORDINATION CHEMISTRY REVIEWS
(2022)
Review
Chemistry, Inorganic & Nuclear
Yun-Nan Gong, Xinyu Guan, Hai-Long Jiang
Summary: This review summarizes the synthesis methods, structural features, and photocatalytic applications of covalent organic frameworks (COFs). Strategies for improving photocatalytic performance and future challenges and prospects are also discussed.
COORDINATION CHEMISTRY REVIEWS
(2023)
Review
Chemistry, Inorganic & Nuclear
Chizoba Ezugwu, Shengwei Liu, Chuanhao Li, Serge Zhuiykov, Soumyajit Roy, Francis Verpoort
Summary: Artificial photosynthesis is a promising technique for CO2 mitigation and solar energy conversion. Metal-organic frameworks (MOFs) are efficient photocatalysts with high surface area and flexible design capabilities for complex multicomponent systems. The review examines strategies for designing MOFs to convert CO2 into solar fuels efficiently, highlighting features as semiconductor photocatalysts and means to improve light-harvesting and CO2 adsorption.
COORDINATION CHEMISTRY REVIEWS
(2022)
Review
Chemistry, Inorganic & Nuclear
S. Vinoth, Wee-Jun Ong, A. Pandikumar
Summary: This article summarizes the importance of BiOX materials in energy and environmental applications. BiOX has a layered structure and high photocatalytic activity, and its physical and chemical properties and photocatalytic activity can be enhanced by controlling defects. The article also discusses the role of defect engineering in improving the performance of BiOX and prospects the future research opportunities.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Lu Chen, Junfeng Wang, Xiaojing Li, Chunran Zhao, Xin Hu, Ying Wu, Yiming He
Summary: A novel Z-scheme photocatalyst Bi-Bi2O3/KTa0.5Nb0.5O3 (KTN) composite was prepared, showing higher photocatalytic ammonia-synthesis efficiency. The incomplete core-shell structure of loaded Bi-Bi2O3 nanoparticles and the presence of Bi metal improved charge separation and electron migration, resulting in enhanced photocatalytic activity.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Review
Chemistry, Inorganic & Nuclear
Sisi Liu, Mengfan Wang, Yanzheng He, Qiyang Cheng, Tao Qian, Chenglin Yan
Summary: COFs, as a subclass of porous framework materials, possess permanent porosity, long-range order, and rigid backbones, offering a significant material platform for addressing global energy and environmental crisis. With the rapid development of various fields, COF-based photocatalysis has achieved remarkable progress and shown immense potential in applications such as gas storage, energy conversion, and organic transformation.
COORDINATION CHEMISTRY REVIEWS
(2023)
Review
Chemistry, Inorganic & Nuclear
Guangfu Wang, Danlian Huang, Min Cheng, Sha Chen, Gaoxia Zhang, Lei Lei, Yashi Chen, Li Du, Ruijin Li, Yang Liu
Summary: Template derivatization of metal-organic frameworks (MOFs) is an effective strategy for preparing functionalized materials. Chemically treated MOF precursors can be transformed into layered double hydroxides (LDHs), which enhance the stability, conductivity, and mass transfer capability of MOFs. This review summarizes the progress of MOF-derived LDHs and discusses their applications in the energy and environment fields.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Huajie Huang, Ya Xue, Yongshuai Xie, Ying Yang, Lu Yang, Haiyan He, Quanguo Jiang, Guobing Ying
Summary: In this study, a controllable assembly approach was proposed to construct a heterostructured nanoarchitecture using ultrafine MoS2 quantum dot-decorated Ti3C2Tx MXene nanosheets (MQDs/Ti3C2Tx). The resulting MQD/Ti3C2Tx catalyst exhibited superior hydrogen evolution reaction (HER) properties due to its remarkable structural features, homogeneous MoS2 distribution, optimized electronic structure, and good electron conductivity.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Review
Chemistry, Inorganic & Nuclear
Xianghong Liu, Wei Zheng, Rahul Kumar, Mahesh Kumar, Jun Zhang
Summary: Conducting polymers (CPs) have attracted significant interest in chemical gas sensors due to their versatile nanostructure, easy synthesis, and good environmental stability. Polyaniline, polypyrrole, and polythiophene are commonly used CPs for gas sensing applications. Manipulating the nanostructure of CPs and combining them with various inorganic components can enhance surface adsorption and electronic interactions, leading to advanced sensors.
COORDINATION CHEMISTRY REVIEWS
(2022)
Review
Chemistry, Inorganic & Nuclear
Farhad Ahmadijokani, Hossein Molavi, Shima Tajahmadi, Mashallah Rezakazemi, Majed Amini, Milad Kamkar, Orlando J. Rojas, Mohammad Arjmand
Summary: Tetracyclines are a family of broad-spectrum antibiotics that persist in aquatic environments and can lead to antibiotic resistance and toxic effects in non-target organisms. Metal-organic frameworks (MOFs) have emerged as effective alternatives due to their photocatalytic and adsorptive capabilities. This review summarizes recent progress in the detection, adsorption, and photocatalytic degradation of tetracyclines in water, discusses the use of MOFs critically, and introduces limitations and future prospects for the development of novel multi-functional MOF-based nanomaterials.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Reza Abazari, Soheila Sanati, Ali Morsali
Summary: In this study, a Fe2Ni MIL-88 composite was synthesized and applied to the oxygen evolution reaction (OER). The composite exhibited remarkable OER activity in alkaline environments, suggesting its high potential for practical applications.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Inorganic & Nuclear
Anees A. A. Ansari, Khalid M. M. Aldajani, Abdulaziz N. N. AlHazaa, Hamad A. A. Albrithen
Summary: This review summarizes the application of nanomaterials in latent fingerprint imaging, with a focus on luminescent Ln(3+)-NPs/UCNPs and their advantages in producing high-quality images on porous and non-porous surfaces. The review also discusses the use of conventional techniques, such as physical, chemical, and instrumental methods, for fingerprint detection, highlighting their limitations. Furthermore, the review emphasizes the need for further research in developing efficient, high-performance, surface-functionalized, biocompatible, and nontoxic Ln(3+) NPs/UCNPs for recognizing latent fingerprints on different surfaces.
COORDINATION CHEMISTRY REVIEWS
(2022)
