期刊
GREEN CHEMISTRY
卷 16, 期 1, 页码 191-196出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41184b
关键词
-
资金
- USDA National Institute of Food and Agriculture, Critical Agricultural Materials program [2010-38202-21853]
Isolated, solvent-extracted lignin from candlenut (Aleurites moluccana) biomass was subjected to catalytic depolymerization in methanol with an added pressure of H-2, using a porous metal oxide catalyst (PMO) derived from a Cu-doped hydrotalcite-like precursor. The Cu-PMO was effective in converting low-molecular weight lignin into simple mixtures of aromatic products in high yield, without char formation. Gel permeation chromatography was used to track changes in molecular weight as a result of the catalytic treatments and product mixtures were characterized by H-1 and C-13 NMR spectroscopy. In the temperature range 140-220 degrees C, unusual C9 catechols were obtained with high selectivity. Lignin conversion of > 90% and recovery of methanol-soluble products in yields of was > 70% was seen at 180 degrees C with optimized catalyst and biomass loadings. At 140 degrees C, 4-(3-hydroxypropyl)-catechol was the major product and could be isolated in high purity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据