期刊
GREEN CHEMISTRY
卷 16, 期 10, 页码 4535-4540出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc00536h
关键词
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资金
- State of Mecklenburg-Western Pomerania
- BMBF
- Evonik
The application of heterogenized non-noble metal-based catalysts in selective catalytic hydrogenation processes is still challenging. In this respect, the preparation of a well-defined cobalt-based catalyst was investigated by immobilization of the corresponding cobalt(II)-phenanthroline-chelate on Vulcan XC72R carbon powder. The formed core-shell structured cobalt/cobalt oxide nanocomposites are encapsulated by nitrogen-enriched graphene layers. This promising cheap heterogeneous catalyst allows for an efficient domino reductive amination of carbonyl compounds with nitroarenes.
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