期刊
GREEN CHEMISTRY
卷 16, 期 7, 页码 3428-3433出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc00723a
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资金
- University of Massachusetts, Amherst
- Catalysis Center for Energy Innovation
- Energy Frontier Research Center - US Dept. of Energy, Office of Science, and Office of Basic Energy Sciences [DE-SC0001004]
Under base free and mild reaction conditions, 80.5% selectivity of lactic acid (LA) was achieved at 89.8% conversion of glycerol using a bifunctional Pt/Sn-MFI catalyst. In the tandem reaction pathway, selective oxidation of glycerol to glyceraldehyde (GLA) and dihydroxyacetone (DHA) was cascaded with Lewis acid catalyzed isomerization of GLA/DHA into LA.
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