期刊
GREEN CHEMISTRY
卷 16, 期 6, 页码 3013-3017出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc42624f
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资金
- National Science Council, Republic of China
- Academia Sinica
Copper-catalyzed alkene oxidation to carbonyl compounds by tert-butyl hydroperoxide (TBHP) under organic solvent-free and biphasic conditions at room temperature is selective for the aromatic gem-disubstituted alkenes. Enhanced reactivity was observed in the presence of 2,9-dimethyl-1,10-phenanthroline (neocuproine). The reaction is economically attractive because the yield is high, and separation of products and recycling of the catalyst are easy.
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