期刊
GREEN CHEMISTRY
卷 15, 期 12, 页码 3295-3301出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41444b
关键词
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资金
- Institute of Chemical Research of Catalonia (ICIQ) Foundation
- MINECO [CTQ2008-00947/BQU, CTQ2012-38594-C02-01]
- DEC [2009SGR623]
- Spanish Government
A polystyrene-supported, pyrrolidine-based catalyst depicting very high activity and excellent stereoselectivity in the anti-Mannich reaction of aldehydes and ketones has been developed. The very robust, immobilized catalyst has been successfully used in the implementation of a continuous flow process with short residence times (down to 6 min) for the production of highly enantioenriched anti-type Mannich adducts at the preparative scale.
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