期刊
GREEN CHEMISTRY
卷 15, 期 6, 页码 1673-1677出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc40729b
关键词
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资金
- Korean Ministry of Education, Science and Technology through the National Research Foundation [2012-001507]
- Department of Science and Technology, New Delhi, India
An environment-friendly synthesis of cyclic carbonates from CO2 and epoxides with a HCOOH/KI catalytic system was performed in a microwave reactor. Various epoxide substrates were subjected to microwave irradiated cycloaddition using a HCOOH/KI catalyst. The effects of reaction parameters like catalyst composition, microwave power, CO2 pressure, and reaction time have been investigated. The synergistic influence of the COOH/KI catalyst in the reaction has been compared with that of an OH/KI system and was theoretically simulated using density functional theory.
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