期刊
GREEN CHEMISTRY
卷 14, 期 1, 页码 143-147出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc16074e
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资金
- National Science Foundation [OISE 0730277, EEC-0813570]
- United States Department of Energy [DE-FG02-95ER14549]
- U.S. Department of Energy (DOE) [DE-FG02-95ER14549] Funding Source: U.S. Department of Energy (DOE)
The mechanism of selective oxidation of aqueous 5-hydroxymethylfurfural (HMF) at high pH was studied over supported Pt and Au catalysts. Results from labeling experiments conducted with O-18(2) and (H2O)-O-18 indicated that water was the source of oxygen atoms during the oxidation of HMF to 2-hydroxymethylfurancarboxylic acid (HFCA) and 2,5-furandicarboxylic acid (FDCA), presumably through direct participation of hydroxide in the catalytic cycle. Molecular oxygen was essential for the production of FDCA and played an indirect role during oxidation by removing electrons deposited into the supported metal particles. A reaction path for HMF oxidation to FDCA was proposed.
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