期刊
GREEN CHEMISTRY
卷 14, 期 4, 页码 1030-1034出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc16427b
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- FAPERGS [PRONEX 10/0005-1, 10/0027-4, PqG 11/1045-8]
- CAPES
- FINEP
- CNPq
We describe herein the use of glycerol as the solvent in the copper-catalyzed cross-coupling reaction of diaryl diselenides with arylboronic acids using CuI and DMSO as additive. This cross-coupling reaction was performed with diaryl diselenides and arylboronic acids bearing electron-withdrawing and electron-donating groups, affording the corresponding diaryl selenides in good to excellent yields. The glycerol-CuI mixture can be directly reused for further cross-coupling reactions.
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