期刊
GREEN CHEMISTRY
卷 14, 期 9, 页码 2457-2461出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc35667h
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资金
- Danish National Advanced Technology Foundation
- Novozymes A/S
- US Department of Agriculture
Catalytic conversion of HMF to valuable chemicals was achieved over a Cu-doped porous metal oxide in supercritical methanol. The hydrotalcite catalyst precursor is prepared following simple synthetic procedures, using inexpensive and earth-abundant starting materials in aqueous solutions. The hydrogen equivalents needed for the reductive deoxygenation of HMF originate from the solvent itself upon its reforming. Dimethylfuran, dimethyltetrahydrofuran and 2-hexanol were obtained in good yields. At milder reaction temperatures, a combined yield (DMF + DMTHF) of 58% was achieved. Notably, the formation of higher boiling side products and undesired char from HMF is not detected under these reaction conditions.
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