4.8 Article

Recyclable and stable ruthenium catalyst for free radical polymerization at ambient temperature initiated by visible light photocatalysis

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GREEN CHEMISTRY
卷 14, 期 3, 页码 618-621

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc16409d

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资金

  1. KOSEF NRL [R0A-2008-000-20068-0]
  2. KCAP (Sogang Univ.) [NRF-2011-C1AAA001-2011-0030278]
  3. Center for Multiscale Energy System [2011-0031571]
  4. Basic Science Research Program [2009-0093462]
  5. NRF [2010-0019119]
  6. MEST (Korea)

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A ruthenium complex catalyst immobilized on Nafion coated silica, SiO2/Nf/RuL, shows recyclable and stable photocatalytic activity for free radical polymerization at ambient temperature under mild visible light irradiation. The stable SiO2/Nf/RuL photocatalyst can be easily recycled by simple washing without chemical treatment, exhibiting high catalytic performance and no notable decrease in catalytic efficiency even after five test cycles.

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