4.8 Article

Easily removable olefin metathesis catalysts

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GREEN CHEMISTRY
卷 14, 期 12, 页码 3264-3268

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36015b

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  1. National Centre for Research and Development
  2. Foundation for Polish Science
  3. European Regional Development Fund, Operational Program Innovative Economy

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A small family of olefin metathesis catalysts bearing a polar quaternary ammonium group is described. The presence of this group allows for efficient separation of ruthenium impurities after the reaction. Application of catalysts 9 and 11 leads to organic products of high purity, which exhibit surprisingly low ruthenium contamination levels (usually below 5 ppm) after a simple and inexpensive purification step.

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