期刊
GREEN CHEMISTRY
卷 14, 期 6, 页码 1666-1672出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc35126a
关键词
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资金
- FCT [SFRH/BD/65699/2009, SFRH/BD/37652/2007]
- QREN/FEDER [PTDC/QUI-QUI/112913/2009]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/65699/2009, SFRH/BD/37652/2007] Funding Source: FCT
This paper describes an environmentally sustainable synthetic method for the preparation of a set of meso-aryl hydroporphyrins, namely chlorins and bacteriochlorins, via reduction of porphyrins with diimide, in the total absence of solvents and bases. Thermomicroscopy studies clearly showed that the process is a typical solvent-free reaction.
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