期刊
GREEN CHEMISTRY
卷 14, 期 1, 页码 94-97出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc16092c
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资金
- DFG training group 1166 BioNoCo (Biocatalysis in non-conventional Media)
A one-pot multi-step approach comprising enzymatic oxidation-hydroxymethylation-reduction enables the synthesis of optically active alpha-aryl vicinal diols with high yields and enantioselectivities. Formaldehyde required for the hydroxymethylation step is enzymatically produced in situ using less hazardous methanol as substrate.
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