期刊
GREEN CHEMISTRY
卷 13, 期 1, 页码 82-90出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00395f
关键词
-
资金
- EPSRC
- Technology and Strategy Board
- Scionix Ltd.
- Engineering and Physical Sciences Research Council [EP/F047991/1] Funding Source: researchfish
- EPSRC [EP/F047991/1] Funding Source: UKRI
In this work the use of glycerol as a hydrogen bond donor in Deep Eutectic Solvents is studied. The physical properties of choline chloride mixtures with glycerol are quantified and it is shown that eutectic mixtures can circumvent some of the difficulties of using glycerol as a solvent viz. high viscosity and high melting point. The solvent properties are characterised using polarity parameters and the values are similar to other ionic liquids although it is shown that this procedure is a poor method of characterising Lewis basicity. The application of these liquids to the esterification of glycerol is used as a demonstration of the ability to tune a reaction with the quaternary ammonium halide acting as a quasi-protecting group. The liquids represent a sustainable way of preparing non-toxic, tuneable solvent systems.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据