期刊
GREEN CHEMISTRY
卷 13, 期 3, 页码 591-593出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00413h
关键词
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资金
- National Natural Science Foundation of China [20872087, 20902057]
- Key Laboratory of Synthetic Chemistry of Natural Substances, Chinese Academy of Sciences
- Shanghai Municipal Education Commission [J50101]
- Shanghai University
CuCl-catalyzed green oxidative homocoupling of terminal alkynes produces symmetrical 1,4-disubstituted 1,3-diynes in good to excellent yields, using air as an environmentally friendly oxidant and the occurrence of water as exclusive byproduct in the whole process, and eliminating the need for ligands, bases, oxidants and expensive palladium catalysts.
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