4.8 Article

Investigating the formation of dialkyl carbonates using high speed ball milling

期刊

GREEN CHEMISTRY
卷 13, 期 11, 页码 3156-3161

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15594f

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资金

  1. National Science Foundation [CHE-0548150]
  2. University of Cincinnati's Research Council (URC)
  3. National Science foundation-iREU
  4. American Chemical Society
  5. Deutscher Akademischer Austausch Dienst

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We investigated the synthesis of dialkyl carbonates under solvent-free high speed ball milling conditions. We converted various metal carbonates with the assistance of metal complexing reagents into a variety of dialkyl carbonates. We also observed the increased reactivity of urea under similar reaction conditions.

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