期刊
GREEN CHEMISTRY
卷 13, 期 4, 页码 843-846出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15106a
关键词
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资金
- Chubu Bureau of Economy Trade and Industry
- [B21390030]
- [22106515]
Solkane (R) 365 mfc is proven to be an environmentally benign alternative solvent for the homocoupling reaction of terminal alkynes catalyzed by CuCl/TMEDA under air at room temperature. A variety of terminal alkynes, including aromatic, heteroaromatic and aliphatic alkynes, were cleanly transformed into 1,3-diynes within a short period in high to excellent yields up to 98%.
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