期刊
GREEN CHEMISTRY
卷 13, 期 6, 页码 1448-1452出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15024c
关键词
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资金
- French-Tunisian joint project PHC-UTIQUE [09G1203]
The ruthenium catalysed cross-metathesis of terpenoids with methyl acrylate and methyl methacrylate was used to prepare new terpenoids and to improve, to a large extent, the synthesis of known terpenoids. In particular, the cross-metathesis of mono-unsaturated terpenoids was very efficient whereas the transformation of terpenoids incorporating two double bonds was more difficult due to side reactions. The cross-metathesis reactions were carried out under environmentally friendly conditions either in dimethyl carbonate or under solvent-free conditions.
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