4.8 Article

Organic dye photocatalyzed alpha-oxyamination through irradiation with visible light

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GREEN CHEMISTRY
卷 12, 期 6, 页码 953-956

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b924609f

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  1. National University of Singapore [R-143-000-337-112]
  2. Medicinal Chemistry Program

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Rose Bengal, an organic dye, was used as a visible light photocatalyst to investigate novel alpha-oxyamination reactions between 1,3-dicarbonyl compounds and a free radical (TEMPO). Compounds that are difficult to obtain such as quaternary fluorinated compounds were synthesized using this method. This visible light photocatalytic reaction can also be performed in water.

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