期刊
GREEN CHEMISTRY
卷 11, 期 9, 页码 1401-1405出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b912521n
关键词
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资金
- National Natural Science Foundation of China [20025205, 20572108]
- Chinese Academy of Sciences
Tetra-(tetraalkylammonium)octamolybdate catalysts are successfully applied in the selective oxidation of various sulfides to sulfoxides with 30% aqueous hydrogen peroxide as oxidant under mild reaction conditions in 94-100% yield and 95-100% selectivity. The octamolybdate catalysts show high catalytic activity in a high ratio of substrate to catalyst (up to 10000:1) and are recyclable, with actively functional groups, including hydroxyl group and C=C bonds, tolerated in the oxidation.
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