期刊
GREEN CHEMISTRY
卷 11, 期 10, 页码 1605-1609出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b913052g
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资金
- European Union [NMP2-CT-2005-011774]
- Spanish MCIMM [CTQ2008-05138, CSD 2006-003]
- Gobierno de Aragon and Caja de Ahorros de la Inmaculada
A family of glycerol-based solvents, consisting of eighteen 1,3-dialkoxy-2-propanols and 1,2,3-trialkoxypropanes, both symmetrically and unsymmetrically substituted at terminal positions, has been tested as new solvents in cyclooctene epoxidation with hydrogen peroxide, using a diselenide catalyst, but also without a catalyst. A quantitative relationship between the reactivity and solvent polarity properties has been developed through statistical linear regression analyses, and the predictive ability of the resulting equation has been demonstrated.
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