期刊
GREEN CHEMISTRY
卷 11, 期 11, 页码 1871-1875出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b913115a
关键词
-
资金
- CNRS
- French Ministry of Research
- European Network IDECAT (NOE) [NMP3-CT-2005-011730]
The ruthenium catalysed direct functionalisation of arene C-H bonds by aryl halides is reported. Reactions were performed in diethyl carbonate (DEC) instead of N-methylpyrrolidone (NMP), the solvent of choice used in most ruthenium catalysed C-H bond transformations. The use of diethyl carbonate facilitates the workup procedure thus reducing the amount of waste water. The slight loss of activity due to the use of diethyl carbonate is counterbalanced by the improvement of the catalyst efficiency achieved by a judicious choice of additives. Several arenes containing an N-heterocycle as a directing group have been diarylated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据