期刊
GREEN CHEMISTRY
卷 11, 期 7, 页码 1052-1055出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b820606f
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资金
- DFG (Deutsche Forschungsgemeinschaft) [GRK 1166]
Enantioselective sulfoxidation was carried out by cascade reaction of Pd(0) catalysed formation of H2O2 and enzymatic oxidation using chloroperoxidase from Caldariomyces fumago. Supercritical carbon dioxide (scCO(2)) was used as medium for in situ generation of H2O2 directly from H-2 and O-2 using Pd-catalysts. Subsequently, H2O2 was utilised by the chloroperoxidase as an oxidant for the asymmetric sulfoxidation in the aqueous phase. This chemo-enzymatic cascade transformation exemplifies the potential of compartmentalisation of catalytic processes in multiphase systems.
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