期刊
GREEN CHEMISTRY
卷 11, 期 11, 页码 1857-1861出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b916265h
关键词
-
资金
- Hong Kong Baptist University [FGR/03-04/II-36, FRG/05-06/II-32]
- Hong Kong Research Grant Council [HKBU 201006]
Oxidation of alkyl substituted aromatic compounds to ketones and carboxylic acids can be achieved by 70% aqueous TBHP (tert-butyl hydroperoxide) under microwave irradiation with no additional organic solvent, metal based reagent or catalyst. Methyl aromatics (toluenes and xylenes) can be oxidized directly to the industrially important benzoic and phthalic acids. An addition of a tiny amount of ionic liquid and simultaneous cooling improves the efficiency of these oxidations. For other alkyl substituted aromatics, ketones are obtained in good yields.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据