期刊
GEOSTANDARDS AND GEOANALYTICAL RESEARCH
卷 35, 期 2, 页码 235-251出版社
WILEY-BLACKWELL
DOI: 10.1111/j.1751-908X.2010.00097.x
关键词
CGSG-1; -5; MPI-DING; reference glasses; reference values; homogeneity; major element composition; trace element composition
资金
- Ministry of Science and Technology of the Peoples Republic of China
Four silicate glasses were prepared by the fusion of about 1 kg powder each of a basalt, syenite, soil and andesite to provide reference materials of natural composition for microanalytical work. These glasses are referred to as 'Chinese Geological Standard Glasses' (CGSG) -1, -2, -4 and -5. Micro and bulk analyses indicated that the glasses are well homogenised with respect to major and trace elements. Some siderophile/chalcophile elements (e.g., Sn, Pt, Pb) may be heterogeneously distributed in CGSG-5. This paper provides the first analytical data for the CGSG reference glasses using a variety of analytical techniques (wet chemistry, XRF, EPMA, ICP-AES, ICP-MS, LA-ICP-MS) performed in nine laboratories. Most data agree within uncertainty limits of the analytical techniques used. Discrepancies in the data for some siderophile/chalcophile elements exist, mainly because of possible heterogeneities of these elements in the glasses and/or analytical problems. From the analytical data, preliminary reference and information values for fifty-five elements were calculated. The analytical uncertainties [2 relative standard error (RSE)] were estimated to be between about 1% and 20%.
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