Effect of biochar on phosphorus sorption and clay soil aggregate stability

Soil structure is one of the key properties affecting the productivity of soils and the environmental side effects of agricultural soils. Poor surface soil structure increases the risk of soil erosion by water and eroded clay-sized particles can carry adsorbed phosphorus (P) to the surface waters, thus inducing eutrophication of receiving waterways. Management practices, e.g. reduced tillage, used to reduce erosion can lead to enrichment of P in the uppermost soil layers, which leads to elevated risk for dissolved P loss in the runoff water. In this study, we aimed to identify whether biochar (BC) could be used to reduce clay soil erosion by improving aggregate stability. Moreover, we tested whether the BC addition would change the P sorption affinity of the soil and help to reduce the loss of dissolved P. One sandy and two clayey soils were amended with BC (0,15 and 30 t ha(-1)) and after a 3week incubation, a wet-sieving method was used to measure the release of colloidal particles and the stability of aggregates. The sorption of P onto soil surfaces was estimated with a Q/I (quantity/intensity) plot technique. The BC used here had a very low P sorption affinity and the BC addition did not increase the sorption of P in incubated soils. However, for the two clayey soils, the BC additions increased aggregate stability and reduced detachment of colloidal material. The BC thus induced changes in soil properties that could be beneficial for erosion control and thereby aid in reducing particulate P losses from agricultural fields. (c) 2014 Elsevier B.V. All rights reserved.