The 87Sr/86Sr and 143Nd/144Nd disequilibrium between Polynesian hot spot lavas and the clinopyroxenes they host: Evidence complementing isotopic disequilibrium in melt inclusions

We report Sr-87/Sr-86 and Nd-143/Nd-144 data on clinopyroxenes recovered from 10 ocean island lavas from three different hot spots (Samoa, Society, and Cook-Austral island chains). The clinopyroxenes recovered from eight of the 10 lavas analyzed in this study exhibit Sr-87/Sr-86 disequilibrium with respect to the host lava. The Sr-87/Sr-86 ratios in clinopyroxene separates are 95-3146 ppm (0.0095-0.31%) different from their respective host whole rocks. Clinopyroxenes in three lavas have Nd-143/Nd-144 ratios that are 70-160 ppm (0.007-0.016%) different from the host lavas. The Sr-87/Sr-86 and Nd-143/Nd-144 disequilibrium in one lava (the oldest lava considered in this study, Mangaia sample MGA-B-47) can be attributed to posteruptive radiogenic ingrowth, but the isotope disequilibrium in the other, younger lavas cannot be explained by this mechanism. In five of the lava samples, two populations of clinopyroxene were isolated (black and green, separated by color). In four out of five of these samples, the Sr-87/Sr-86 ratios of the two clinopyroxene populations are isotopically different from each other. In addition to Sr-87/Sr-86 disequilibrium, the two clinopyroxene populations in one of the lavas (Tahaa sample TAA-B-26) have Nd-143/Nd-144 ratios that are similar to 100 ppm different from each other. Given the resilience of clinopyroxene to seawater alteration and the likelihood that the Sr and Nd isotope composition of fresh clinopyroxene separates provides a faithful record of primary magmatic compositions, the clinopyroxene-clinopyroxene isotope disequilibrium in these four lavas provides strong evidence that a mechanism other than seawater alteration has generated the observed isotopic disequilibrium. This study confirms the isotopic diversity in ocean island lavas previously observed in olivine-hosted melt inclusions. For example, the Sr isotopic variability previously observed in olivine-hosted melt inclusions is mirrored by the isotopic diversity in clinopyroxenes isolated from many of the same Samoan lavas. The isotopic data from melt inclusions and clinopyroxenes are not consistent with shallow assimilation of sediment or with entrainment of xenocrystic clinopyroxene from the oceanic crust or upper mantle. Instead, the data are interpreted as reflecting isotopic heterogeneity in the mantle sources of the lavas. The isotopic diversity in clinopyroxenes and melt inclusions suggests that a single lava can host components derived from isotopically diverse source regions.