4.7 Article

Esterification of fatty acids with alcohols over niobium phosphate

期刊

FUEL PROCESSING TECHNOLOGY
卷 106, 期 -, 页码 619-624

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.fuproc.2012.09.054

关键词

Esterification; Niobium phosphate; Niobium; Fatty acids

资金

  1. CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico)
  2. FAPERJ (Fundacao de Amparo a Pesquisa do Rio de Janeiro)
  3. ANP (Agencia Nacional de Petroleo) [PRH1]

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The aim of this study is the evaluation of niobium catalysts (niobic acid, niobium phosphate) in the esterification reactions of fatty acids (C12-C18) with alcohols (methanol, ethanol, butanol). The catalysts were characterized by different techniques (N-2 adsorption/desorption, XRD, FTIR, FTIR of adsorbed pyridine). The niobium phosphate was the most active in esterification of lauric acid with butanol and can be reutilized three times without loss of activity. (C) 2012 Elsevier B.V. All rights reserved.

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