4.4 Article

Spatially Resolved Voltage, Current and Electrochemical Impedance Spectroscopy Measurements

期刊

FUEL CELLS
卷 11, 期 2, 页码 339-349

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/fuce.201000181

关键词

Diagnostics; Electrochemical Impedance Spectroscopy; Multichannel System; Polymer Electrolyte Membrane Fuel Cell; Pulse Technique; Sensing Electrodes Spatially Resolved Measurements

资金

  1. Bundesministerium fur Bildung und Forschung (BMBF) [03SF0360A]

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In this work a 50-channel characterisation system for PEMFCs is presented. The system is capable of traditional electrochemical measurements (e. g. staircase voltammetry, chronoamperometry and cyclic voltammetry), and concurrent EIS measurements. Unlike previous implementations, this system relies on dedicated potentiostats for current and voltage control, and independent frequency response analysers (FRAs) at each channel. Segmented fuel cell hardware is used to illustrate the system's flexibility and capabilities. The results here include steady-state data for cell characterisation under galvanostatic and potentiostatic control as well as spatially resolved impedance spectra.

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