期刊
FUEL
卷 113, 期 -, 页码 435-442出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2013.06.008
关键词
Biodiesel; Kraft lignin; Solid base catalyst; Transesterification; K2CO3
资金
- National Basic Research Program of China [2012CB215305, 2012CB215306]
- National Science Foundation of China [21172209]
- Chinese Academy of Science [KJCX2-EW-J02]
- Engineering Research Center of Biomass Materials(SWUST), Ministry of Education [12zxbk05]
In this study, the catalysts K2CO3 supported Kraft lignin activated carbon (K2CO3/KLC) were prepared in situ by simply mixing K2CO3 with technical Kraft lignin (KL) and subsequently activating at 800 degrees C for 2 h under N-2 flow. The precursor and catalysts were characterized by thermal gravity analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) surface area. The catalytic performance of prepared catalysts was evaluated by transesterification of rapeseed oil with methanol. The effects of various parameters on biodiesel yield were investigated. The biodiesel yield of 99.6% was achieved by using the catalyst prepared by 0.6 of K2CO3/KL mass ratio and activation at 800 degrees C, under the transesterification condition of 65 degrees C, 2 h, methanol to rapeseed oil molar ratio of 15:1 and 3.0 wt.% catalyst (relative to the weight of rapeseed oil). The solid catalyst can be reused for 4 times and biodiesel yield remained over 82.1% for the fourth time. (C) 2013 Elsevier Ltd. All rights reserved.
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