期刊
FUEL
卷 105, 期 -, 页码 306-313出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2012.06.062
关键词
Biodiesel; Antioxidants; Surfactants; Electroanalysis; Screen-printed electrodes
资金
- CAPES
- CNPq
- Fundacao de Apoio ao Desenvolvimento do Ensino, Ciencia e Tecnologia do Estado de Mato Grosso do Sul - FUNDECT
An electroanalytical method for the simultaneous detection and quantification of tert-butylhydroquinone (TBHQ) and butyl hydroxyanisole (BHA) in biodiesel was developed using a voltammetric technique and screen-printed electrodes. The supporting electrolyte solution was composed of Britton-Robinson buffer (0.04 mol L-1) containing methanol (2.0%) and the cationic surfactant cetyltrimethylammonium bromide (CTAB). In the presence of CTAB, the peak current intensity and voltammetric resolution increased significantly for both studied antioxidants. Using the optimized conditions, the method presented a linear response in the concentration range of 5.0 x 10(-7)-1.0 x 10(-5) mol L-1 for TBHQ (r = 0.999) and BHA (r = 0.999) with detection limits of 3.40 x 10(-7) mol L-1 and 1.76 x 10(-7) mol L-1, respectively. The proposed method was successfully applied for the quantification of TBHQ and BHA in biodiesel samples after a simple and rapid dilution with recoveries from 97.90% to 110.0% and 91.90% to 101.0%, respectively. The obtained results were satisfactory when compared with those obtained using high-performance liquid chromatography (HPLC). Additionally, the proposed method can be easily adapted for on-site analysis. (C) 2012 Elsevier Ltd. All rights reserved.
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