期刊
FUEL
卷 94, 期 1, 页码 624-628出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2011.10.011
关键词
Carbon dioxide; Post-combustion; CaO looping cycle; Synthetic CaO; Sol-gel method
In this study a synthetic calcium oxide sorbent was prepared using a sol-gel synthesis method. The synthesized CaO and a reference CaO, obtained through the calcination of commercial CaCO3, were characterized by means of X-ray diffraction, N-2 adsorption and SEM microscopy. For the reference CaO, results from cyclic carbonation and calcination showed the typical behavior described in the literature. Conversely, the synthetic CaO, with a coral like morphology and higher surface area (45 m(2)/g), maintained its reactivity throughout 18 cycles, losing 55% over 70 consecutive cycles, with a residual reactivity value of 0.24 g(CO2)/g(CaO). The morphology and structural changes of the synthesized CaO sample were examined and a deactivation mechanism was suggested. (C) 2011 Elsevier Ltd. All rights reserved.
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