Mitigation of NOx emissions from a jatropha biodiesel fuelled DI diesel engine using antioxidant additives

Biodiesel offers cleaner combustion over conventional diesel fuel including reduced particulate matter, carbon monoxide and unburned hydrocarbon emissions. However, several studies point to slight increase in NOx emissions (about 10%) for biodiesel fuel compared with conventional diesel fuel. Use of antioxidant additives is one of the most cost-effective ways to mitigate the formation of prompt NOx. In this study, the effect of antioxidant additives on NOx emissions in a jatropha methyl ester fuelled direct injection diesel engine have been investigated experimentally and compared. A survey of literature regarding the causes of biodiesel NOx effect and control strategies is presented. The antioxidant additives L-ascorbic acid, a tocopherol acetate, butylated hydroxytoluene, p-phenylenediamine and ethylenediamine were tested on computerised Kirloskar-make 4 stroke water cooled single cylinder diesel engine of 4.4 kW rated power. Results showed that antioxidants considered in the present study are effective in controlling the NOx emissions of biodiesel fuelled diesel engines. A 0.025%-m concentration of p-phenylenediamine additive was optimal as NOx levels were substantially reduced in the whole load range in comparison with neat biodiesel. However, hydrocarbon and CO emissions were found to have increased by the addition of antioxidants. (C) 2011 Elsevier Ltd. All rights reserved.