Investigation on the structure and the oxidation activity of the solid carbon produced from catalytic decomposition of methane

The structure and the oxidation activity of the solid carbon produced from catalytic decomposition of methane at different temperatures were investigated using TEM, XRD, Raman and TPO techniques. The results show that the graphitization degree of the solid carbon is increased with decomposition reaction temperature. The addition of ethylene or acetylene to methane can change the growth way of the solid carbon and decrease their graphitization degree. The average oxidation temperature of the solid carbon has a close relationship with the corresponding graphitization degree. The addition of ethylene or acetylene to methane can decrease the average oxidation temperature of the solid carbon. (C) 2009 Elsevier Ltd. All rights reserved.