Thermal decomposition of pyrotechnic mixtures containing either aluminum or magnesium powder as fuel

Thermal behavior of energetic materials is critical to safe production, storage, handling or even demilitarization. In this work, the thermal behavior of Al, Mg, CuO, KmnO(4) and also three mixtures containing Al + CuO, Mg + CuO and Mg + KMnO4 were studied experimentally using differential scanning calorimetry and thermogravimetry. These mixtures are sometimes used as pyrotechnic mixtures in military industries. Also, the influence of different heating rates (5, 10, 15 and 20 degrees C/min) on the DSC behavior of the mixtures was verified. The results showed that as the heating rate was increased, melting points and ignition temperatures of the mixtures were increased. On the other hand, TG-DSC analysis for Mg + KMnO4 mixture indicates that this mixture melts at 283.0 degrees C and decomposed at 292.1 degrees C. By replacing KmnO(4) with CuO as the oxidizer of the magnesium, these temperatures enhanced to 368.7 degrees C and 408.3 degrees C, respectively. However, replacing Mg with Al in the Mg/CuO mixture decreases the melting and ignition temperatures of the mixture to 231.4 degrees C and 271.9 degrees C, respectively. The activation energy for each pyrotechnic mixture was computed. Also, the values of Delta S-#, Delta H-# and Delta G# of their reaction were calculated. (C) 2007 Elsevier Ltd. All rights reserved.