Influence of xanthan gum on physical characteristics of sodium caseinate solutions and emulsions

Influence of xanthan gum (XG) on the properties of the solution containing 3.0 wt% sodium caseinate (CN) was estimated firstly by zeta potential, hydrodynamic diameter (D-H) and interfacial tension. CN-XG mixture solutions showed larger DH and lower negative zeta potential at higher XG concentration, indicating that molecule interactions may take place in solution. The surface activity of CN was improved with addition of XG at 0.01 wt%, while it weakened to a great extent at 0.04 wt% XG. Then, the influence of XG on the concentrated (36 wt%) emulsion, stabilized with 3.0 wt% CN was assessed by droplet diameter and dispersion characteristics, apparent viscosity, surface protein concentration and microstructure. Results showed that emulsion without XG, characterized by the lowest surface protein concentration and apparent viscosity, showed no sign of flocculation but coarse oil droplets. Increase in XG concentration led to an increase followed by a decrease in d(4,3), uniformity values and partial coalescence of fat, while inversely, surface protein concentration decreased firstly and then increased. CLSM images showed extensive enrichment region of XG and depletion flocculation at XG concentration above 0.01 wt%. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.