Gelation behaviour and rheological properties of acid-induced soy protein-stabilized emulsion gels

The protein concentration dependence on the rheological properties of acid-induced gels formed with unheated and heated soy protein-stabilized emulsions (UHSPE and HSPE) was investigated at different acidification temperatures. Pre-heat treatment on soy protein solutions resulted in a higher storage modulus (G') and a shorter gelation time (t(gel)) of acid-induced emulsion gels. A maximum in tan delta was observed in the UHSPE gels but no maximum was detected in the HSPE gels. Increasing the acidification temperature decreased the G' and t(gel). The dependence of the G' on the protein concentration (c) can be scaled with a power law: G' similar to c(A). The exponent (A) increased with pre-heat treatment and acidification temperature. The experimental data. fitted the fractal scaling model (G' similar to phi(A)) and the simple time-scaling model above very well for the acid-induced soy protein-stabilized HSPE gels with varying oil volume fraction. The large deformation and fracture properties were significantly affected by soy protein concentration, pre-heat treatment, acidification temperature and volume fraction of oil droplets (p < 0.05). Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.