期刊
FOOD CHEMISTRY
卷 158, 期 -, 页码 497-503出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2014.02.129
关键词
Honey; Botanical origin; Multidimensional gas chromatography; Separation of enantiorners; Solid phase microextraction (SPME); Chiral volatile organic compounds (VOC's)
资金
- VEGA [1/0972/12]
- Science and Technology Assistance Agency [APVV-0428-12]
- Slovak University of Technology
The enantiomer ratios of chiral volatile organic compounds in rapeseed, chestnut, orange, acacia, sunflower and linden honeys were determined by multi-dimensional gas chromatography using solid phase microextraction (SPME) as a sample pre-treatment procedure. Linalool oxides, linalool and hotrienol were present at the highest concentration levels, while significantly lower amounts of alpha-terpineol, 4-terpineol and all isomers of lilac aldehydes were found in all studied samples. On the other hand, enantiomer distribution of some chiral organic compounds in honey depends on their botanical origin. The significant differences in enantiomer ratio of linalool were observed for rapeseed honey that allows us to distinguish this type of honey from the other ones. The enantiomer ratios of lilac aldehydes were useful for distinguishing of orange and acacia honey from other studied monofloral honeys. Similarly, different enantiomer ratio of 4-terpineol was found for sunflower honeys. (C) 2014 Elsevier Ltd. All rights reserved.
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