Phenolic content and antioxidant capacity of hybrid variety cocoa beans

Cocoa (Theobroina cacao L.) is a major, economically important, international crop and has been associated with several nutritional benefits including high antioxidant capacity. New cocoa hybrids have been developed in Ghana that exhibit resistance to pest damage during storage. The aim of this work was to assess the phenolic content and antioxidant capacity of these new hybrids in comparison to more traditional cocoa varieties. Total extractable phenolics were similar in all the four hybrids tested ranging from 69.9 to 81.6 FAE g(-1). These levels were very similar to that extracted from traditional beans (73.8 +/- 2.5 FAE g(-1)). The phenolic profile was determined by HPLC. A total of 25 peaks was observed but there were only minor differences in this profile between traditional and hybrid bean extracts. Antioxidant capacity was determined using the FRAP assay and traditional beans were found to possess 12.4 mu mol TE g(-1). In comparison the hybrid beans had antioxidant capacities ranging from 21.6 to 45.5 mu mol TE g(-1), and these were significantly higher than in the traditional beans for three out of the four hybrids. Since the phenolic and antioxidant levels and in these hybrid varieties were either similar to, or higher than, that obtained from traditional beans, the introduction of these new varieties would be unlikely to impact detrimentally on these nutritional components of the beans. (C) 2007 Elsevier Ltd. All rights reserved.