期刊
FERROELECTRICS
卷 432, 期 -, 页码 65-72出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00150193.2012.707854
关键词
Perovskite; ceramics; phase transition; diffuseness parameters
资金
- Natural Science Foundation of China [51002036, 21061004, 50962004]
- Natural Science Foundation of Guangxi [BA053007, C013002]
- Projects of the Department of Science and Technology of Guangxi [12118017-13, 0842003, 09-007-02]
A perovskite solid solution of (1-x)(Bi0.5Na0.5)TiO3-x(Na0.5K0.5)NbO3 (BNT-xNKN) (x = 0-0.08) synthesized by solid state reaction technique exhibits diffuse phase transition (DPT) behavior. Power law, Gauss-type quadratic law and Lorenz-type quadratic law was employed to characterize the dielectric permittivity peaks near T-m. The diffuseness parameters gamma, delta(G) and delta(A) increase with the increase in the value of x, which implies a composition-induced diffuse transition. Among these laws simulating dielectric response in diffusion ferroelectric phase transition, the Lorenz-type quadratic law is the best to describe the characterization of DPT behavior in such a wide temperature range as observed in our experiment.
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