4.2 Article

Dimeric ortho-palladated complex of 2,3-dimethoxybenzaldehyde oxime catalyzed Suzuki-Miyaura cross-coupling reaction under microwave irradiation

期刊

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
卷 12, 期 7, 页码 1177-1181

出版社

SPRINGER
DOI: 10.1007/s13738-014-0579-3

关键词

ortho-Palladated catalyst; Palladacycle complexes; Oxime; Suzuki reaction; Biaryls

资金

  1. Isfahan University of Technology (IUT), IR Iran
  2. Isfahan Science & Technology Town (ISTT), IR, Iran
  3. Center of Excellence in Sensor and Green Chemistry Research (IUT)
  4. research council of Alzahra University

向作者/读者索取更多资源

The catalytic activity of dimeric [Pd{C6H2(-CH=NOH)-(OMe)(2)-2,3}(A mu-Cl)](2) complex as an efficient, air, and moisture-tolerant catalyst was investigated in Suzuki cross-coupling reactions of various aryl halides. The combination of homogenous metal catalyst, microwave irradiation, and microwave-active polar solvents gave high yields of substituted biaryl products in short reaction times.

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